536731-11-0Relevant articles and documents
Asymmetric induction during Yang cyclization of α-oxoamides: The power of a covalently linked chiral auxiliary is enhanced in the crystalline state
Natarajan, Arunkumar,Mague, Joel T.,Ramamurthy
, p. 3568 - 3576 (2007/10/03)
γ-Hydrogen abstraction has been revealed to be the primary photoprocess in the crystalline state of α-oxoamides through photochemical and X-ray structural studies. The outstanding ability of a covalent chiral auxiliary in generating asymmetric induction i