53685-78-2Relevant academic research and scientific papers
HYDROALUMINATION OF ALLYL ALCOHOLS AND ETHERS BY LITHIUM ALUMINUM HYDRIDE IN THE PRESENCE OF ZIRCONIUM CATALYST
Sato, Fumie,Tomuro, Yasuji,Ishikawa, Hiroaki,Sato, Masao
, p. 99 - 102 (2007/10/02)
Allyl alcohols and ethers were readily hydroaluminated by LiAlH4 in the presence of zirconium compounds to give organoaluminum compounds in which the aluminum atom is placed at the terminal position of the substrate.ZrCl4 was the most effective catalyst for hydroalumination of allyl alcohols, whilst Cp2ZrCl2 was more effective than ZrCl4 for allyl ethers.
