537036-27-4

Upstream product

• 358-23-6 trifluoromethylsulfonic anhydride 
• 79271-56-0 triethylsilyl trifluoromethyl sulfonate 
• 537036-26-3 (2S,3R,5S,6R)-5-benzyloxy-6-(2-benzyloxyethyl)-2-hydroxymethyl-6-methyltetrahydropyran-3-ol 
• 537036-24-1 (4R,5S)-4-[(2S,3R)-3-(2-benzyloxyethyl)-3-methyl-2-(toluene-4-sulfonyl)oxiranylmethyl]-2,2-di-tert-butyl-5-(triethylsilyloxy)-[1,3,2]dioxasilinane 
• 537036-48-9 (4aS,6R,7S,8aR)-7-Benzyloxy-6-(2-benzyloxy-ethyl)-2,2-di-tert-butyl-6-methyl-hexahydro-1,3,5-trioxa-2-sila-naphthalene 
• 537036-47-8 (4aS,6R,7S,8aR)-6-(2-Benzyloxy-ethyl)-2,2-di-tert-butyl-6-methyl-hexahydro-1,3,5-trioxa-2-sila-naphthalen-7-ol 
• 537036-25-2 (4aS,6R,8aR)-6-(2-benzyloxyethyl)-2,2-di-tert-butyl-6-methyldecahydro-1,3,5-trioxa-2-silanaphthalen-7-one 

Downstream Products

• 537036-45-6 3-benzyloxy-2-(2-benzyloxy-ethyl)-11-[3-(tert-butyl-diphenyl-silanyloxymethyl)-3-methyl-2-(toluene-4-sulfonyl)-oxiranylmethyl]-2,10-dimethyl-10-trimethylsilanyloxy-octadecahydro-1,5,7,12,14-pentaoxa-cyclohepta[b]naphthacene 
• 537036-38-7 8-[2-benzenesulfonyl-3-(tert-butyl-diphenyl-silanyloxymethyl)-oxiranylmethyl]-3-benzyloxy-2-(2-benzyloxy-ethyl)-2-methyl-9-triethylsilanyloxy-tetradecahydro-1,5,7,11-tetraoxa-naphthacene 
• 537036-35-4 (2R,3S,4aR,6R,7S,8aR,9aS,10aS)-7-[(2S,3R)-2-Benzenesulfonyl-3-(tert-butyl-diphenyl-silanyloxymethyl)-oxiranylmethyl]-3-benzyloxy-2-(2-benzyloxy-ethyl)-2-methyl-6-triethylsilanyloxy-decahydro-1,8,10-trioxa-anthracene 
• 537036-58-1 C₅₇H₇₄O₁₀Si 
• 537036-46-7 C₅₇H₇₂O₁₀Si 
• 537036-32-1 (2R,3S,4aR,6S,7R,8aS)-6-[(2S,3R)-2-Benzenesulfonyl-3-(tert-butyl-diphenyl-silanyloxymethyl)-oxiranylmethyl]-3-benzyloxy-2-(2-benzyloxy-ethyl)-2-methyl-7-triethylsilanyloxy-octahydro-pyrano[3,2-b]pyran 
• 537036-56-9 (2R,3S,4aR,5aS,6aR,7aS,10R,11S,12aR,13aS,14aR,15aS)-3-Benzyloxy-2-(2-benzyloxy-ethyl)-11-(tert-butyl-diphenyl-silanyloxymethyl)-2,10-dimethyl-octadecahydro-1,5,7,12,14-pentaoxa-cyclohepta[b]naphthacen-10-ol 
• 537036-42-3 C₅₃H₆₆O₉Si 
• 537036-41-2 [(2R,3S,4aR,5aS,6aR,7aS,11R,12aR,13aS,14aR,15aS)-3-Benzyloxy-2-(2-benzyloxy-ethyl)-2-methyl-10-methylene-octadecahydro-1,5,7,12,14-pentaoxa-cyclohepta[b]naphthacen-11-ylmethoxy]-tert-butyl-diphenyl-silane 
• 537036-40-1 (2R,3S,4aR,5aS,6aR,7aS,11S,12aR,13aS,14aR,15aS)-3-Benzyloxy-2-(2-benzyloxy-ethyl)-11-(tert-butyl-diphenyl-silanyloxymethyl)-2-methyl-hexadecahydro-1,5,7,12,14-pentaoxa-cyclohepta[b]naphthacen-10-one 
• 537036-39-8 (2S,4aS,5aR,6aS,7aR,9S,10R,11aS,12aR,13aS,14aR)-9-Benzyloxy-10-(2-benzyloxy-ethyl)-2-(tert-butyl-diphenyl-silanyloxymethyl)-10-methyl-tetradecahydro-1,5,7,11,13-pentaoxa-pentacen-3-one 
• 537036-44-5 Trifluoro-methanesulfonic acid (2R,3S,4aR,5aS,6aR,7aS,10R,11S,12aR,13aS,14aR,15aS)-3-benzyloxy-2-(2-benzyloxy-ethyl)-2,10-dimethyl-10-trimethylsilanyloxy-octadecahydro-1,5,7,12,14-pentaoxa-cyclohepta[b]naphthacen-11-ylmethyl ester 
• 537036-37-6 Trifluoro-methanesulfonic acid (2S,3R,4aS,5aR,6aS,8R,9S,10aR,11aS,12aR)-9-benzyloxy-8-(2-benzyloxy-ethyl)-8-methyl-3-triethylsilanyloxy-tetradecahydro-1,5,7,11-tetraoxa-naphthacen-2-ylmethyl ester 
• 537036-54-7 (2S,3R,4aS,5aR,6aS,8R,9S,10aR,11aS,12aR)-9-Benzyloxy-8-(2-benzyloxy-ethyl)-2-(tert-butyl-diphenyl-silanyloxymethyl)-8-methyl-tetradecahydro-1,5,7,11-tetraoxa-naphthacen-3-ol 

Relevant academic research and scientific papers

Iterative synthesis of the ABCDEF-ring system of yessotoxin and adriatoxin

A stereocontrolled linear synthesis of the ABCDEF-ring system of yessotoxin and adriatoxin, diarrhetic shellfish toxins, is described. Iterative application of a tetrahydropyran synthesis by reaction of the alkylation of a sulfonyl-stabilized oxiranyl ani