53742-67-9Relevant academic research and scientific papers
The Role of Silicon-Oxygen Interactions in Determining the Stereochemical Outcome of the Peterson Reaction
Bassindale, Alan R.,Ellis, Richard J.,Taylor, Peter G.
, p. 34 - 35 (2007/10/03)
The electronic effect of substituents on a benzene ring on the stereochemical outcome of the reaction of an α-triarylsilyl carbanion with an aldehyde is examined: the results can be interpreted in terms of the mode of approach of the carbanion towards the prochiral aldehyde, taking into account a variable oxygen-silicon interaction.
The reaction of isosteric isobutyl(isopropoxy)silanes iBun(iPrO)3-nSiH (n = 0-3) with allyl bromide in the presence of platinum compounds
Pikies, J.,Wojnowski, W.
, p. 187 - 193 (2007/10/02)
The isosteric silanes iBun(iPrO)3-nSiH react with allyl bromide to yield the corresponding bromides iBun(iPrO)3-nSiBr.The reactivities of the silanes fall in the sequence: iBu(iPrO)2SiH iBu2(iPrO)SiH > (iPrO)3SiH > iBu3SiH which can be accounted for in terms of the anomeric effects at the silicon atom.
The Mechanism of the Reaction of Molecular Bromine with Organosilicon Hydrides
El-Durini, Nabil M. K.,Jackson, Richard A.
, p. 1275 - 1278 (2007/10/02)
The kinetics of the bromination of 7 triarylsilanes and 14 other organosilicon hydrides by molecular bromine in CCl4 have been determined by the stopped flow method.For triethylsilane, Arrhenius parameters have been measured in octane and CCl4, and solvent effects determined in other solvents of different polarity.The results accord with a molecular mechanism involving one molecule of bromine and one of the organosilicon hydride, with partial positive charge build-up on silicon in the transition state.
