53793-56-9Relevant academic research and scientific papers
Pyridine-based lanthanide complexes: Towards bimodal agents operating as near infrared luminescent and MRI reporters
Pellegatti, Laurent,Zhang, Jian,Drahos, Bohuslav,Villette, Sandrine,Suzenet, Franck,Guillaumet, Gerald,Petoud, Stephane,Toth, Eva
supporting information; experimental part, p. 6591 - 6593 (2009/04/20)
We report two prototype Ln3+ complexes that address requirements for both MRI and luminescence imaging and we demonstrate that the presence of two H2O molecules bound to the Ln3+, beneficial for MRI applications of the Gd3+ analogue, is not a major limitation for the development of NIR luminescent agents. The Royal Society of Chemistry 2008.
New Heteroaromatic Complexing Agents and Luminescence of Their Europium(III) and Terbium(III) Chelates
Mukkala, Veli-Matti,Sund, Christian,Kwiatkowski, Marek,Pasanen, Paavo,Hoegberg, Marita,et al.
, p. 1621 - 1632 (2007/10/02)
Twelve heteroaromatic complexing agents 9a-l were synthesized with the purpose to develop suitable labels for time-resolved luminescence-based bioaffinity assays.The relative luminescence yields, excitation maxima, and emission decay constants of their europium(III) and terbium(III) chelates were determined.According to these results, 2,2',2'',2'''-tetrakis(acetic acid) (9e) and 2,2',2'',2'''-tetrakis(acetic acid) (9l) are the most promising agents.
Acidic Complexones Bearing Donor-enhancing Pyridine Anchour Groups
Voegtle, Fritz,Ohm, Christian
, p. 948 - 954 (2007/10/02)
The synthesis, complex stability and -selectivity for alkaline earth metal ions 2,6-pyridinebis(methylamine)-N,N,N',N'-tetraacetic acids (3a) and their donor-enforced analogues 3b,c are described.The acid dissociation constants and the stability constants of the metal complexes have been measured potentiometrically at 25 deg C in water of constant ionic strength (μ = 0.1).The stability order is Ca > Mg > Sr > Ba which is analogous to the selectivity of EDTA and comparable aliphatic complexones.The magnitudes of the stability constants of 3a are comparable to those of EDTA, while the donor-enforced analogues 3b,c form less stable complexes with alkaline earth metal ions.
