5384-70-3Relevant academic research and scientific papers
Thermal behavior of Spiroozonides from formaldehyde-O-oxide and tropone derivatives: A coarctate reaction
Berger, Christian,Dieterich, Stefan,Dilger, Ulrich,Geuenich, Daniel,Helios, Heike,Herges, Rainer,Kirchmer, Peter,Roettele, Herbert,Schroeder, Gerhard
, p. 1854 - 1857 (1998)
Spiroozonides of tropones undergo an unusually facile fragmentation via the coarctate Mobius transition state 1. The ozonides are generated from formaldehyde O-oxide and tropone derivatives at -90°C. Depending on the substitution, they fragment at temperatures between -60 to +50°C to give carbon dioxide, formaldehyde, and benzene derivatives.
