53856-43-2Relevant academic research and scientific papers
Transition-Metal π-Ligation of a Tetrahalodiborane
Braunschweig, Holger,Dewhurst, Rian D.,Jiménez-Halla, J. Oscar C.,Matito, Eduard,Muessig, Jonas H.
, p. 412 - 416 (2018)
The reaction of tetraiododiborane (B2I4) with trans-[Pt(BI2)I(PCy3)2] gives rise to the diplatinum(II) complex [{(Cy3P)(I2B)Pt}2(μ2:η3:η3-B2I4)], which is supported by a bridging diboranyl dianion ligand [B2I4]2?. This complex is the first transition-metal complex of a diboranyl dianion, as well as the first example of intact coordination of a B2X4 (X=halide) unit of any type to a metal center.
Interaction between d- and p-block metals: Synthesis and structure of platinum-alane adducts
Braunschweig, Holger,Gruss, Katrin,Radacki, Krzysztof
, p. 7782 - 7784 (2008/09/18)
(Figure Presented) You'll never walk alane: An intriguing T-shaped platinum-alane adduct results from the almost quantitive reaction of [Pt(PCy3)2] with AlX3 (X = Cl, Br, I). The compound [(Cy3P)2Pt-A
Chemistry of metal hydrides- 25. Reactions of trans-[PtH2(P-c-Hx3)2] with carbon monoxide and other π acids
Andorson, Gordor K.,Citric, Howard C.,Davies, Julian A.
, p. 550 - 553 (2008/10/08)
The complex trans reacts with carbon monoxide at low temperature to yield the reductive elimination of being reversible at 298 K.
