53920-49-3Relevant academic research and scientific papers
Synthesis of 2-pyridylthiophosphinic acids and 2-pyridylthiophosphonate monoesters via nucleophilic aromatic substitution
Oka, Natsuhisa,Ori, Kensuke,Ando, Kaori
, p. 454 - 463 (2017)
In this study, we developed a method for the synthesis of 2-pyridylthiophosphinic acids and 2-pyridylthiophosphonate monoesters using easily accessible starting materials, H-phosphinate and H-phosphonate esters and pyridine N-oxides. The H-phosphinate and
Synthesis of 2-pyridylphosphinate and thiophosphinate derivatives by nucleophilic aromatic substitution of N-methoxypyridinium tosylates
Oka, Natsuhisa,Ito, Kousuke,Tomita, Futoshi,Ando, Kaori
supporting information, p. 1630 - 1632 (2013/02/23)
We developed a straightforward and cost-effective method for the synthesis of 2-pyridylphosphinate derivatives based on a nucleophilic aromatic substitution of N-methoxypyridinium salts. The method proved to be useful for synthesizing various 2-pyridylphosphinates and thiophosphinates, including an optically active compound, from H-phosphinate precursors.
