54100-54-8

Upstream product

• 39095-25-5 2,5-dimethylbenzene-1,4-dicarbonitrile 
• 6051-66-7 2,5-dimethylterephthalic acid 
• 1074-24-4 2,5-dibromo-p-xylene 
• 54100-53-7 2,5-dimethylterephthalic acid, dimethyl ester 

Downstream Products

• 66212-59-7 12,15-Dimethoxy<2.2>paracyclophan-4,7-dicarbonsaeure-dimethylester 
• 87402-52-6 2,5-Bis(mercaptomethyl)-terephthalsaeure-dimethylester 
• 87387-08-4 N,N'-Bis(benzyloxycarbonyl)<3.3>paracyclophan-5,8-diamin 
• 87387-01-7 14,17-Bis(benzyloxycarbonylamino)<3.3>paracyclophan-5,8-diacetonitril 
• 1321601-42-6 C₃₈H₃₆O₆S₂ 
• 1321601-41-5 C₄₀H₄₀O₈S₂ 

Relevant academic research and scientific papers

Tuning Supramolecular Polymer Assembly through Stereoelectronic Interactions

The supramolecular polymerization of 2,11-dithia[3.3]paracyclophanes through self-complementary intermolecular and transannular amide hydrogen bonding is presented. An n → π? interaction between the amide hydrogen bonding units and the central bridging at

METHODS FOR IDENTIFYING PROTEINS BY USING SYNTHETIC RECEPTORS

The invention relates to oligomeric macrocycles and to uses thereof as receptors for recognition of protein post-translational modifications (PTM) or specific motifs in proteins.

Optical resolution, absolute configuration, and chiroptical properties of three-layered [3.3]paracyclophane

(Figure Presented) A racemic mixture of three-layered [3.3]paracyclophane ([3.3]PCP), 1, has been resolved into two enantiomers, and their absolute configuration was determined from a comparison of experimental chiroptical properties and density functiona

A Selective Receptor for Arginine Derivatives in Aqueous Media. Energetic Consequences of Salt Bridges That Are Highly Exposed to Water

Quantitative measures of salt-bridge-type interactions in a highly exposed aqueous environment have been obtained by modifying the well-studied cyclophane platform 1 to include carboxylates in close proximity to bound, cationic guests, producing hosts 2 and 3. Many guests show significantly enhanced binding to 2 and 3, but cations of the RNMe3+ type show little or no enhancement. We propose that the latter observations result from the fact that RNMe3+ compounds have very diffuse positive charges. Guests that show enhanced binding have focused regions of large, positive electrostatic potential. The highly charged 3 is able to bind very polar, very well-solvated guests, including a series of arginine-based dipeptides. Neutral, water-soluble host 4 was prepared and found to show a decreased affinity for cationic guests. We propose a novel induced dipole mechanism to rationalize these results.