54206-20-1Relevant academic research and scientific papers
Synthesis of [Pt12(CO)20(dppm)2]2- and [Pt18(CO)30(dppm)3]2- Heteroleptic Chini-type Platinum Clusters by the Oxidative Oligomerization of [Pt6(CO)12
Berti, Beatrice,Cesari, Cristiana,Conte, Francesco,Ciabatti, Iacopo,Femoni, Cristina,Iapalucci, Maria Carmela,Vacca, Federico,Zacchini, Stefano
, p. 7578 - 7590 (2018)
The reactions of [Pt6(CO)12]2- with CH(PPh2)2 (dppm), CH2=C(PPh2)2 (P^P), and Fe(C5H4PPh2)2 (dppf) proceed via nonredox sub
Unexpected substitution reactions of bis(phosphine)platinum ethene complexes
Chaloner, Penny A.,Broadwood-Strong, Gillian T. L.
, p. 1039 - 1043 (2007/10/03)
Reaction of [Pt(C2H4)(PR3)2] (R = Ph or C6H4Me-4) with moderately bulky phosphines at low temperatures did not give the expected tris- or tetrakis-phosphine complexes. Instead, mixed-phosph
MIXED LIGAND COMPLEXES OF PLATINUM(0) CONTAINING DIPHOSPHINES
Clark, Howard C.,Kapoor, Pramesh N.,McMahon, Ian J.
, p. 107 - 116 (2007/10/02)
The reaction of PtCl2L (L = diphosphine) with the appropriate diphosphine L' in ethanol followed by reduction with aqueous sodium borohydride leads to either disproportionation to give mixtures of the bis(diphosphine) complexes PtL2 and PtL'2 or to the fo
