54338-82-8Relevant academic research and scientific papers
NEW AND EFFICIENT DEHALOGENATIVE COUPLING AND REDUCTION OF α-HALOKETONES WITH ACTIVE NICKEL COMPLEX. FACILE SYNTHESES OF 1,4-DIKETONES AND BICYCLOOCT-3-ENE-2,5-DIONES
Iyoda, Masahiko,Sakaitani, Masahiro,Kojima, Atsuko,Oda, Masaji
, p. 3719 - 3722 (2007/10/02)
The active nickel complex generated in situ by reduction of NiBr2(PPh3)2 with zinc in the presence of Et4NI is a useful reagent for the dehalogenative coupling of phenacyl halides to 1,4-diaryl-1,4-diketones and for the dechlorination of 3,4-dichlorobicyclo-octane-2,5-diones to bicyclooct-3-ene-2,5-diones.
