54354-02-8

Basic information

• Product Name: tert-butyl 2-benzoylbenzoate
• CAS NO: 54354-02-8
• Molecular Formula: C₁₈H₁₈O₃
• Molecular Weight: 282.3337
• Mol File: 54354-02-8.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 382.6°C at 760 mmHg
• Flash Point: 166.3°C
• Density: 1.107g/cm³
• Vapor Pressure: 4.67E-06mmHg at 25°C
• Refractive Index: 1.553
• CAS DataBase Reference: tert-butyl 2-benzoylbenzoate(CAS DataBase Reference)
• NIST Chemistry Reference: tert-butyl 2-benzoylbenzoate(54354-02-8)
• EPA Substance Registry System: tert-butyl 2-benzoylbenzoate(54354-02-8)

Safety Data

• Hazardous Substances Data: 54354-02-8(Hazardous Substances Data)

Upstream product

• 55666-42-7 tert-butyl 2-bromobenzoate 
• 98-88-4 benzoyl chloride 
• 85-52-9 2-Benzoylbenzoic acid 
• 75-65-0 tert-butyl alcohol 
• 774-65-2 benzoic acid tert-butyl ester 
• 604-61-5 ethyl 2-benzoylbenzoate 
• 115-11-7 isobutene 

Downstream Products

• 22103-85-1 2-benzoylbenzoyl chloride 
• 101278-30-2 β-phenyl-2-carboxycinnamic acid 

Relevant articles and documents

Synthesis of Functionalized Ketones from Acid Chlorides and Organolithiums by Extremely Fast Micromixing

Synthesis of ketones containing various functional groups from acid chlorides bearing electrophilic functional groups and functionalized organolithiums was achieved using a flow microreactor system. Extremely fast mixing is important for high chemoselectivity.

PREPARATION AND USE OF MAGNESIUM AMIDES

The present application relates to mixed Mg/Li amides of the general formula R1R2N-Mg-NR3R4.zLiY (II) wherein R1, R2, R3, and R4 are, independently, selected from H, substituted or unsubstituted aryl or heteroaryl containing one or more heteroatoms, linear, branched or cyclic, substituted or unsubstituted alkyl, alkenyl, alkynyl, or silyl derivatives thereof; and R1 and R2 together, or R3 and R4 together can be part of a cyclic or polymeric structure; and wherein at least one of R1 and R2 and at least one of R3 and R4 is other than H; Y is selected from the group consisting of F; Cl; Br; I; CN; SCN; NCO; HaIOn, wherein n = 3 or 4 and Hal is selected from Ci, Br and I; NO3; BF4; PF6; H; a carboxylate of the general formula RxCO2; an alcoholate of the general formula ORx; a thiolate of the general formula SRx; RxP(O)O2; or SCORx; or SCSRx; OnSRx, wherein n = 2 or 3; or NOn, wherein n = 2 or 3; and a derivative thereof; wherein Rx is a substituted or unsubstituted aryl or heteroaryl containing one or more heteroatoms, linear, branched or cyclic, substituted or unsubstituted alkyl, alkenyl, alkynyl, or derivatives thereof, or H; m is O or 1; and z > 1; as well as a process for the preparation of the mixed Mg/Li amides and the use of these amides, e.g. as bases.