54458-23-0Relevant articles and documents
New halo compounds of Si, P, As, and Sb bearing a bulky substituted fluorenyl group
Baiget,Bouslikhane,Escudie,Nemes, G. Cretiu,Silaghi-Dumitrescu,Silaghi-Dumitrescu
, p. 1949 - 1961 (2003)
New halo compounds of Si, P, As, and Sb, potential precursors of doubly-bonded derivatives of these elements, have been synthesized: dichloro-and difluorosilanes 2-6 bearing a methylfluorenyl group and a second substituent of various size (Me, Ph, Mes, R
Synthesis of Mono-, Di-, and Trinuclear Rhodium Diphosphine Complexes Containing Light-Harvesting Fluorene Backbones
Matsusaka, Yuko,Shitaya, Shoji,Nomura, Kotohiro,Inagaki, Akiko
, p. 1027 - 1030 (2017)
Syntheses and structural determination of rhodium complexes ligated by diphosphines containing light-harvesting fluorene backbones are presented. In these rhodium complexes, the rhodium center is surrounded by a light-absorbing diphosphine unit. The presence of Rh-Rh bonding interactions is suggested by density functional theory studies.
Lewis Acid Enables Ketone Phosphorylation to Form a C-P Bond and a C-C Bond: Synthesis of 9-Phosphoryl Fluorene Derivatives
Wei, Xiao-Hong,Bai, Chun-Yuan,Wang, Ai-Jun,Feng, Qiao-Liang,Zhao, Lian-Biao,Zhang, Ping,Li, Zhen-Hua,Su, Qiong,Wang, Yan-Bin
, p. 7100 - 7105 (2021/09/14)
An efficient method for the Lewis acid promotion of the synthesis 9-phosphoryl fluorenes has been reported. This method focuses on ketone phosphonylation to form a C-P bond and a C-C bond between diphenylmethanone and H-phosphinate esters, H-phosphites, and H-phosphine oxides via phospha-aldol elimination, in which a series of 9-phosphoryl fluorene derivatives were selectively obtained in moderate to excellent yields.
