54498-70-3

Basic information

• Product Name: <4-D1>Cyclohexanon
• CAS NO: 54498-70-3
• Molecular Weight: 99.1369
• Mol File: 54498-70-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: <4-D1>Cyclohexanon(CAS DataBase Reference)
• NIST Chemistry Reference: <4-D1>Cyclohexanon(54498-70-3)
• EPA Substance Registry System: <4-D1>Cyclohexanon(54498-70-3)

Safety Data

• Hazardous Substances Data: 54498-70-3(Hazardous Substances Data)

Upstream product

• 23511-05-9 toluene-4-sulfonic acid 1,4-dioxa-spiro[4.5]dec-8-yl ester 

Relevant articles and documents

Hydrogen Transfer Reactions, 19. - The Catalysis of Hydrogen Transfer and 1,5-H Shift by Rhodium(III) Chloride in Homogeneous Organic Systems

In homogeneous solution, partly in the presence of a phase-transfer catalyst, rhodium(III) chloride catalyzes the disproportionation of 1,3-cyclohexadiene and to a lesser extent 1,5-H shifts.In the start phase the catalyst is reduced to the active monovalent state.In these catalytic systems the dehydrogenation proceeds stereoselectively. - This was shown by tracer experiments and isotopes effects using deuterated 1,3-cyclohexadienes 1a-d, which were synthesized with high isotopomeric purity.Key Words: Rhodium chloride / Hydrogen transfer / Deuterated 1,3-cyclohexadienes / Isotope effects