54509-72-7Relevant academic research and scientific papers
Selective and effective iodination of alkyl-substituted benzenes with elemental iodine activated by Selectfluor F-TEDA-BF4
Stavber, Stojan,Kralj, Petra,Zupan, Marko
, p. 598 - 600 (2007/10/03)
Selective direct introduction of an iodine atom into alkyl-substituted benzene derivatives was effectively achieved by reaction of target molecules with elemental iodine in the presence of 1-chloromethyl-4-fluoro- 1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate) (Selectfluor F-TEDA-BF4). The number of iodine atoms introduced could be modulated by the molar ratio between substrate, iodine and F-TEDA-BF4.
PREPARATION OF AROMATIC IODIDES FROM BROMIDES VIA THE REVERSE HALOGEN EXCHANGE
Suzuki, Hitomi,Kondo, Akiko,Ogawa, Takuji
, p. 411 - 412 (2007/10/02)
Aromatic bromides undergo halogen exchange reaction with iodide ion in the presence of copper(I) iodide in hot hexamethylphosphoric triamide, to give the corresponding iodides in good to moderate yields.
A Mild and Convenient Procedure for Conversion of Aromatic Compounds into Their Iodides Using Ammonium Hexanitratocerate(IV)
Sugiyama, Takashi
, p. 2847 - 2848 (2007/10/02)
Polymethylbenzenes, polymethoxybenzenes, and naphthalene are iodinated with tetrabutylammonium iodide, alkali metal iodides, or molecular iodine in the presence of ammonium hexanitrocerate(IV).Ammonium hexanitrocerate(IV) behaves as a catalyst in the latter system, whereas it is a reagent in the former two.
