54517-55-4Relevant articles and documents
A MODEL FOR TRITERPENE SIDE-CHAIN SYNTHESIS
Gibson, Joseph R.,Reusch, William
, p. 55 - 59 (1983)
Although the hindered CO function in trans-1,6-dimethyl-2-methoxybicyclononan-7-one (1) resists nucleophilic addition and is prone to enolate formation, good yields of addition products from trimethylsilyl cyanide, methylenetriphenylphosphorane and
GLYCALS IN STEREOSPECIFIC SYNTHESIS. I. SYNTHESIS OF (+)-cis-DISPARLURE - THE SEX PHEROMONE OF THE GYPSY MOTH (Porthetria dispar L.)
Tolstikov, A. G.,Khakhalina, N. V.,Odinokov, V. N.,Khalilov, L. M.,Spirikhin L. V.
, p. 263 - 268 (2007/10/02)
An original approach to the synthesis of 2R,3S-epoxy-1-hydroxytridecane was developed on the basis of tri-O-acetyl-D-galactal.The product was used as the key synthon in the production of a sample of (+)-cis-disparlure with high optical purity.