54532-96-6Relevant academic research and scientific papers
Do the electronic effects of sulfur indeed control the π-selectivity of γ-sulfenyl enones? An investigation
Yadav, Veejendra K.,Babu, K. Ganesh,Parvez, Masood
, p. 3866 - 3874 (2007/10/03)
The electronic effects of sulfur in γ-sulfenyl enones are not transmitted to the carbonyl carbon through the π bond as reported previously. The diastereoselectivity is rather controlled by a combination of several other factors. The steric effects arising
Thiosulfonic S-Esters; 6. Fluoride-Mediated α-Phenylsulfenylation of Cyclic Ketones and Esters via their Trimethylsilyl Enol Ethers
Caputo, Romualdo,Ferreri, Carla,Palumbo, Giovanni
, p. 464 - 466 (2007/10/02)
Ketones and carboxylic acid esters are conveniently converted to their α-sulfenylated derivatives.This new procedure is likely to represent the first reliable one for regiospecific monosulfenylation of carbonyl compounds.It is based on the reaction of the
