545358-12-1

Basic information

• Product Name: 6,6-bis[N-(1'R)-(1'-phenyl-2'-hydroxyethyl)carbamoyl]dibenzo[a,c]-1,3-cycloheptadiene
• CAS NO: 545358-12-1
• Molecular Weight: 520.628
• Mol File: 545358-12-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 6,6-bis[N-(1'R)-(1'-phenyl-2'-hydroxyethyl)carbamoyl]dibenzo[a,c]-1,3-cycloheptadiene(CAS DataBase Reference)
• NIST Chemistry Reference: 6,6-bis[N-(1'R)-(1'-phenyl-2'-hydroxyethyl)carbamoyl]dibenzo[a,c]-1,3-cycloheptadiene(545358-12-1)
• EPA Substance Registry System: 6,6-bis[N-(1'R)-(1'-phenyl-2'-hydroxyethyl)carbamoyl]dibenzo[a,c]-1,3-cycloheptadiene(545358-12-1)

Safety Data

• Hazardous Substances Data: 545358-12-1(Hazardous Substances Data)

Upstream product

• 56613-80-0 D-2-phenylglycinol 
• 6672-66-8 5,7-dihydro-dibenzo[a,c]cycloheptene-6,6-dicarboxylic acid diethyl ester 
• 109339-05-1 dibenzo[a,c]-1,3-cycloheptadiene-6,6-dicarboxylic acid 

Relevant articles and documents

Novel chiral dibenzo[a,c]cycloheptadiene bis(oxazoline) and catalytic enantioselective cyclopropanation of styrene

A series of chiral C2-symmetric bis(oxazoline) ligands containing dibenzo[a,c]cycloheptadiene units were synthesized. The copper complexes, prepared in situ from copper (I)-triflate and the new enantiopure oxazoline ligands, were assessed as chiral catalysts in the enantioselective cyclopropanation of styrene with diazoacetate. Enantioselectivities up to 82 and 62%, respectively, for trans- and cis-2-phenylcyclopropanecarboxylate were observed.