545445-84-9

Upstream product

• 4795-29-3 TETRAHYDROFURFURYLAMINE 
• 96-76-4 2,4-di-tert-Butylphenol 
• 50-00-0 formaldehyd 

Downstream Products

• 545445-85-0 Zr[tBu-ONPyrO]Bn₂ 
• 545445-86-1 Hf[tBu-ONPyrO]Bn₂ 
• 545445-86-1 ((C₄H₉)2C₆H₂OCH₂)2NCH₂C₄H₇OHf(CH₂C₆H₅)2 
• 545445-87-2 ((C₄H₉)2C₆H₂OCH₂)2NCH₂C₄H₇OTi(CH₂C₆H₅)2 
• 545445-85-0 ((C₄H₉)2C₆H₂OCH₂)2NCH₂C₄H₇OZr(CH₂C₆H₅)2 

Relevant academic research and scientific papers

Catalyst-Sidearm-Induced Stereoselectivity Switching in Polymerization of a Racemic Lactone for Stereocomplexed Crystalline Polymer with a Circular Life Cycle

Construction of robust, stereocomplexed (sc) crystalline material, based on a recently discovered infinitely recyclable polymer system, requires blending of enantiomeric polymer chains produced from respective enantiopure, fused six-five bicyclic lactones

Synthesis and characterization of rare-earth metal guanidinates stabilized by amine-bridged bis(phenolate) ligands and their application in the controlled polymerization of rac-lactide and rac-β-butyrolactone

Eight rare-earth metal guanidinates supported by a versatile family of chelating amine-bridged bis(phenolate) ligands were synthesized. Metathesis reactions of rare-earth metal chlorides [LnClL1(THF)] stabilized by amine-bridged bis(phenolate)

Effects of pendant ligand binding affinity on chain transfer for 1-hexene polymerization catalyzed by single-site zirconium amine bis-phenolate complexes

The kinetics of 1-hexene polymerization using a family of five zirconium amine bis-phenolate catalysts, Zr[tBu-ONXO]Bn2 (where X = THF (1), pyridine (2), NMe2 (3), furan (4), and SMe (5)), has been investigated to uncover

Comparison of selected zirconium and hafnium amine bis(phenolate) catalysts for 1-hexene polymerization

The kinetics of 1-hexene polymerization using a family of three zirconium and hafnium amine bis-phenolate catalysts, M[t-Bu-ONXO]Bn2 (where M = Zr (a) or Hf (b), and X = THF (1), pyridine (2), or NMe2 (3)), have been inves

Structure and magnetic behaviour of mono- and bimetallic chromium(III) complexes of amine-bis(phenolate) ligands

Two lithium amine-bis(phenolate) and four chromium(iii) amine-bis(phenolate) complexes have been prepared. The diprotonated tripodal tetradentate ligand precursors 2-tetrahydrofurfuryl-N,N-bis(2-methylene-4- methyl-6-tert-butylphenol), H2[Osub

Accelerated syntheses of amine-bis(phenol) ligands in polyethylene glycol or "on water" under microwave irradiation

Pure amine-bis(phenol) ligands are readily accessible in high yield, often >90%, when the Mannich condensation reactions are performed "on water" or in poly(ethyleneglycol) (PEG). Microwave-assisted synthesis dramatically reduces the time and energy required to prepare these molecules, typically from 24 h to 5 min. The approach seems to be widely applicable (7 amines and 5 phenols were tested to yield a diverse set of bis(phenol) ligands). Significant improvements in yield were observed for ligands derived from di-tert-amyl and di-tert-butyl phenols, possibly resulting from a hydrophobic effect. Single crystal X-ray diffraction data for the ligand derived from p-cresol and N,N-dimethylethylenediamine is reported.

Iron(III) amine-bis(phenolate) complexes as catalysts for the coupling of alkyl halides with aryl Grignard reagents

Catalytic cross-coupling of aryl Grignard reagents with primary and secondary alkyl halides bearing β-hydrogens is achieved using Fe(III) amine-bis(phenolate) halide complexes. The Royal Society of Chemistry.