54564-61-3Relevant academic research and scientific papers
IMINATION OF SULFUR-CONTAINIG COMPOUNDS. XXVI. IMINATION OF N-SUBSTITUTED TRICHLOROMETHANESULFENAMIDES BY N-CHLOROCARBOXAMIDE
Koval', I. V.,Tarasenko, A. I.,Panchenko, I. S.,Molchanova, N. R.
, p. 1538 - 1541 (2007/10/02)
The decrease in the electron density at the sulfur atom in N-acyl- and N-(arylsulfonyl)trichloromethanesulfenamides under the influence of electron-withdrawing trichloromethyl, acyl, and arylsulfonyl groups is compensated in the N-anion as a result of a displacement of the electronic charge from the nitrogen atom.This promotes the imination of the compounds by N-chlorocarboxamides.
