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5460-31-1 Usage

Chemical Properties

Yellow to brown crystalline powder

Uses

2-Methyl-3-nitrophenol was used as internal standard to develop a method for measurement of stable isotope ratio of methylnitrophenols in atmospheric particulate matter.

Check Digit Verification of cas no

The CAS Registry Mumber 5460-31-1 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 5,4,6 and 0 respectively; the second part has 2 digits, 3 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 5460-31:
(6*5)+(5*4)+(4*6)+(3*0)+(2*3)+(1*1)=81
81 % 10 = 1
So 5460-31-1 is a valid CAS Registry Number.
InChI:InChI=1/C7H7NO3/c1-5-6(8(10)11)3-2-4-7(5)9/h2-4,9H,1H3

5460-31-1 Well-known Company Product Price

  • Brand
  • (Code)Product description
  • CAS number
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  • Alfa Aesar

  • (A13002)  2-Methyl-3-nitrophenol, 96%   

  • 5460-31-1

  • 1g

  • 370.0CNY

  • Detail
  • Alfa Aesar

  • (A13002)  2-Methyl-3-nitrophenol, 96%   

  • 5460-31-1

  • 5g

  • 1095.0CNY

  • Detail
  • Alfa Aesar

  • (A13002)  2-Methyl-3-nitrophenol, 96%   

  • 5460-31-1

  • 25g

  • 4653.0CNY

  • Detail

5460-31-1SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name 2-Methyl-3-nitrophenol

1.2 Other means of identification

Product number -
Other names o-methyl-m-hydroxynitrobenzene

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:5460-31-1 SDS

5460-31-1Synthetic route

3-nitro-o-tolylamine
603-83-8

3-nitro-o-tolylamine

3-nitro-o-cresol
5460-31-1

3-nitro-o-cresol

Conditions
ConditionsYield
With sulfuric acid; sodium nitrite In water83%
Stage #1: 3-nitro-o-tolylamine With sulfuric acid; sodium nitrite In water at 0℃;
Stage #2: With sulfuric acid; water Reflux;
67%
Diazotization;
With sulfuric acid; water; sodium nitrite Diazotization;
(i) NaNO2, aq. H2SO4, (ii) CuSO4; Multistep reaction;
6-methoxy-2-nitrotoluene
4837-88-1

6-methoxy-2-nitrotoluene

3-nitro-o-cresol
5460-31-1

3-nitro-o-cresol

Conditions
ConditionsYield
With boron tribromide In dichloromethane at -5 - 20℃; for 12h; Inert atmosphere;69.7%
ortho-cresol
95-48-7

ortho-cresol

A

3-nitro-o-cresol
5460-31-1

3-nitro-o-cresol

B

2,2'-dimethyl-4,4'-biphenol
612-84-0

2,2'-dimethyl-4,4'-biphenol

C

4,4'-dihydroxy-3,3'-dimethyl-5,5'-dinitrobiphenyl
112036-07-4

4,4'-dihydroxy-3,3'-dimethyl-5,5'-dinitrobiphenyl

D

4,4'-dihydroxy-3,3'-dimethyl-6-nitrobiphenyl
112036-06-3

4,4'-dihydroxy-3,3'-dimethyl-6-nitrobiphenyl

Conditions
ConditionsYield
With ammonium cerium(IV) nitrate In acetic acid for 16h; Ambient temperature;A 20%
B 20%
C 35%
D 20%
With ammonium cerium(IV) nitrate In acetic acid for 16h; Ambient temperature;A 20%
B 20%
C 35%
D 20%
With ammonium cerium(IV) nitrate In water for 1h; Ambient temperature;A 16%
B 12%
C 28%
D 16%
With ammonium cerium(IV) nitrate Ambient temperature; water or acetic acid;A 16%
B 12%
C 28%
D 16%
With ammonium cerium(IV) nitrate; acetic acid Ambient temperature; water or acetic acid;A 16%
B 12%
C 28%
D 16%
2-methoxy-3-methyl-4-nitro-aniline
861609-40-7

2-methoxy-3-methyl-4-nitro-aniline

A

3-nitro-o-cresol
5460-31-1

3-nitro-o-cresol

B

6-methoxy-2-nitrotoluene
4837-88-1

6-methoxy-2-nitrotoluene

Conditions
ConditionsYield
With sulfuric acid; sodium nitrite Diazotization;
beim Diazotieren und Verkochen der schwefelsauren Diazoniumloesung;
sulfuric acid
7664-93-9

sulfuric acid

3-nitro-o-tolylamine
603-83-8

3-nitro-o-tolylamine

3-nitro-o-cresol
5460-31-1

3-nitro-o-cresol

Conditions
ConditionsYield
Verkochen.Diazotization;
2,6-dinitrotoluene
606-20-2

2,6-dinitrotoluene

3-nitro-o-cresol
5460-31-1

3-nitro-o-cresol

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: alcohol; hydrogen sulfide; ammoniacal
2: concentrated sulfuric acid; water; sodium nitrite / Diazotization
View Scheme
2-methoxy-3-methylaniline
18102-30-2

2-methoxy-3-methylaniline

3-nitro-o-cresol
5460-31-1

3-nitro-o-cresol

Conditions
ConditionsYield
Multi-step reaction with 4 steps
2: nitric acid
3: concentrated hydrochloric acid
4: beim Diazotieren und Verkochen der schwefelsauren Diazoniumloesung
View Scheme
acetic acid-(2-methoxy-3-methyl-anilide)
143359-98-2

acetic acid-(2-methoxy-3-methyl-anilide)

3-nitro-o-cresol
5460-31-1

3-nitro-o-cresol

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: nitric acid
2: concentrated hydrochloric acid
3: beim Diazotieren und Verkochen der schwefelsauren Diazoniumloesung
View Scheme
acetic acid-(2-methoxy-3-methyl-4-nitro-anilide)
861548-37-0

acetic acid-(2-methoxy-3-methyl-4-nitro-anilide)

3-nitro-o-cresol
5460-31-1

3-nitro-o-cresol

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: concentrated hydrochloric acid
2: beim Diazotieren und Verkochen der schwefelsauren Diazoniumloesung
View Scheme
6-chloro-2-nitrotoluene
83-42-1

6-chloro-2-nitrotoluene

3-nitro-o-cresol
5460-31-1

3-nitro-o-cresol

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: [(2-di-cyclohexylphosphino-3,6-dimethoxy-2’,4’,6’-triisopropyl-1,1‘-biphenyl)-2-(2‘-amino-1,1’-biphenyl)]palladium(II) methanesulfonate; caesium carbonate / toluene / 16 h / 70 °C / Inert atmosphere
2: boron tribromide / dichloromethane / 12 h / -5 - 20 °C / Inert atmosphere
View Scheme
3-nitro-o-cresol
5460-31-1

3-nitro-o-cresol

amino-6 hydroxy-2 toluene
53222-92-7

amino-6 hydroxy-2 toluene

Conditions
ConditionsYield
palladium on charcoal In ethanol100%
palladium on charcoal In ethanol100%
With palladium 10% on activated carbon; hydrogen In methanol at 20℃; for 24h;99%
3-nitro-o-cresol
5460-31-1

3-nitro-o-cresol

benzyl bromide
100-39-0

benzyl bromide

2-benzyloxy-6-nitrotoluene
20876-37-3

2-benzyloxy-6-nitrotoluene

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 20℃; for 3h;100%
With caesium carbonate In N,N-dimethyl-formamide at 20℃; for 3h;87%
With potassium carbonate In N,N-dimethyl-formamide at 60℃; for 12h; Inert atmosphere;48.6%
3-nitro-o-cresol
5460-31-1

3-nitro-o-cresol

(2-chloroethyl)dimethylamine hydrochloride
4584-46-7

(2-chloroethyl)dimethylamine hydrochloride

dimethyl{2-[(2-methyl-3-nitrophenyl)oxy]ethyl}amine
1089278-90-9

dimethyl{2-[(2-methyl-3-nitrophenyl)oxy]ethyl}amine

Conditions
ConditionsYield
With potassium carbonate In water; butan-1-ol at 80℃; for 13h;100%
3-nitro-o-cresol
5460-31-1

3-nitro-o-cresol

tert-butyldimethylsilyl chloride
18162-48-6

tert-butyldimethylsilyl chloride

tert-butyldimethyl(2-methyl-3-nitrophenoxy)silane
188645-92-3

tert-butyldimethyl(2-methyl-3-nitrophenoxy)silane

Conditions
ConditionsYield
With 1H-imidazole In dichloromethane at 20℃; for 3h; Inert atmosphere;99%
With 1H-imidazole In tetrahydrofuran at 20℃; for 16h;76%
With 1H-imidazole In dichloromethane; N,N-dimethyl-formamide at 20℃;
With 1H-imidazole In dichloromethane; N,N-dimethyl-formamide at 20℃;
3-nitro-o-cresol
5460-31-1

3-nitro-o-cresol

<2H9>trimethylsulphoxonium iodide
23726-00-3

<2H9>trimethylsulphoxonium iodide

1-(methoxy-d3)-2-methyl-3-nitrobenzene
253305-67-8

1-(methoxy-d3)-2-methyl-3-nitrobenzene

Conditions
ConditionsYield
With potassium carbonate at 65℃; for 18h; Sealed tube;99%
3-nitro-o-cresol
5460-31-1

3-nitro-o-cresol

chloroacetone
78-95-5

chloroacetone

2-Methyl-1-nitro-3-(2'-oxopropyloxy)benzene
187267-85-2

2-Methyl-1-nitro-3-(2'-oxopropyloxy)benzene

Conditions
ConditionsYield
With potassium carbonate In acetone for 15h; Heating;98%
With potassium carbonate In acetone at 60℃; for 16h;
3-nitro-o-cresol
5460-31-1

3-nitro-o-cresol

benzyl chloride
100-44-7

benzyl chloride

2-benzyloxy-6-nitrotoluene
20876-37-3

2-benzyloxy-6-nitrotoluene

Conditions
ConditionsYield
With sodium ethanolate In ethanol for 8h; Heating;94%
With potassium carbonate In N,N-dimethyl-formamide at 90℃; for 3h;90%
With potassium carbonate
3-nitro-o-cresol
5460-31-1

3-nitro-o-cresol

methyl iodide
74-88-4

methyl iodide

6-methoxy-2-nitrotoluene
4837-88-1

6-methoxy-2-nitrotoluene

Conditions
ConditionsYield
With sodium hydride In N,N-dimethyl-formamide94%
With sodium hydride In N,N-dimethyl-formamide at 90℃; for 0.333333h;
Stage #1: 3-nitro-o-cresol With sodium hydride In N,N-dimethyl-formamide; mineral oil at 0 - 20℃;
Stage #2: methyl iodide In N,N-dimethyl-formamide; mineral oil at 80℃; for 5h;
With potassium carbonate In N,N-dimethyl-formamide at 20℃; for 14h;
With sodium hydride In N,N-dimethyl-formamide; mineral oil at 20℃; Inert atmosphere;502 mg
3-nitro-o-cresol
5460-31-1

3-nitro-o-cresol

acetic anhydride
108-24-7

acetic anhydride

3-(acetylamino)-2-methylphenyl acetate
76064-16-9

3-(acetylamino)-2-methylphenyl acetate

Conditions
ConditionsYield
Stage #1: 3-nitro-o-cresol; palladium 10% on activated carbon In methanol at 20℃; under 760.051 Torr;
Stage #2: acetic anhydride With pyridine In ethyl acetate for 2h; Heating / reflux;
94%
3-nitro-o-cresol
5460-31-1

3-nitro-o-cresol

2-bromobutyric acid ethyl ester
533-68-6

2-bromobutyric acid ethyl ester

ethyl 2-(2-methyl-3-nitrophenoxy)butanoate
97817-56-6

ethyl 2-(2-methyl-3-nitrophenoxy)butanoate

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide for 18h;91%
(S)-(-)-1-tert-butoxycarbonyl)-2-pyrrolidinemethanol

(S)-(-)-1-tert-butoxycarbonyl)-2-pyrrolidinemethanol

3-nitro-o-cresol
5460-31-1

3-nitro-o-cresol

diethylazodicarboxylate
1972-28-7

diethylazodicarboxylate

t-butyl (2S)-2-[(2-methyl-3-nitrophenoxy)methyl]pyrrolidine-1-carboxylate
474000-39-0

t-butyl (2S)-2-[(2-methyl-3-nitrophenoxy)methyl]pyrrolidine-1-carboxylate

Conditions
ConditionsYield
With triphenylphosphine In tetrahydrofuran91%
3-nitro-o-cresol
5460-31-1

3-nitro-o-cresol

phenylboronic acid
98-80-6

phenylboronic acid

2-methyl-1-nitro-3-phenoxybenzene
930790-12-8

2-methyl-1-nitro-3-phenoxybenzene

Conditions
ConditionsYield
With copper diacetate; triethylamine In dichloromethane at 23℃; for 76h; Molecular sieve;91%
3-nitro-o-cresol
5460-31-1

3-nitro-o-cresol

toluene-4-sulfonic acid 2-(5-methyl-2-phenyl-oxazol-4-yl)-ethyl ester
170861-68-4

toluene-4-sulfonic acid 2-(5-methyl-2-phenyl-oxazol-4-yl)-ethyl ester

5-methyl-4-[2-(2-methyl-3-nitrophenoxy)ethyl]-2-phenyl-1,3-oxazole
748154-36-1

5-methyl-4-[2-(2-methyl-3-nitrophenoxy)ethyl]-2-phenyl-1,3-oxazole

Conditions
ConditionsYield
With caesium carbonate In acetonitrile at 20 - 60℃; for 18h;90%
With caesium carbonate In acetonitrile at 20 - 70℃; for 19h;78%
homoalylic alcohol
627-27-0

homoalylic alcohol

3-nitro-o-cresol
5460-31-1

3-nitro-o-cresol

C11H13NO3
1152500-30-5

C11H13NO3

Conditions
ConditionsYield
With di-isopropyl azodicarboxylate; triphenylphosphine In tetrahydrofuran90%
3-nitro-o-cresol
5460-31-1

3-nitro-o-cresol

bromoacetic acid methyl ester
96-32-2

bromoacetic acid methyl ester

methyl (2-methyl-3-nitrophenoxy)acetate
1089691-61-1

methyl (2-methyl-3-nitrophenoxy)acetate

Conditions
ConditionsYield
With potassium carbonate In acetonitrile at 120℃; for 0.05h; Microwave irradiation;90%
2-bromopentane
107-81-3

2-bromopentane

3-nitro-o-cresol
5460-31-1

3-nitro-o-cresol

1-(2-pentyloxy)-2-methyl-3-nitrobenzene

1-(2-pentyloxy)-2-methyl-3-nitrobenzene

Conditions
ConditionsYield
With potassium carbonate In ethanol Solvent; Reagent/catalyst; Reflux;88.1%
iodomethane-d3
865-50-9

iodomethane-d3

3-nitro-o-cresol
5460-31-1

3-nitro-o-cresol

1-(methoxy-d3)-2-methyl-3-nitrobenzene
253305-67-8

1-(methoxy-d3)-2-methyl-3-nitrobenzene

Conditions
ConditionsYield
With potassium hydroxide In dimethyl sulfoxide for 0.25h; Methylation;87%
3,4-dihydro-2H-pyran
110-87-2

3,4-dihydro-2H-pyran

3-nitro-o-cresol
5460-31-1

3-nitro-o-cresol

2-Methyl-3-nitro-1-(α-tetrahydropyranyloxy)benzene
188185-74-2

2-Methyl-3-nitro-1-(α-tetrahydropyranyloxy)benzene

Conditions
ConditionsYield
With hydrogenchloride In N,N-dimethyl-formamide for 72h; Ambient temperature;82%
2-Methoxyethoxymethyl chloride
3970-21-6

2-Methoxyethoxymethyl chloride

3-nitro-o-cresol
5460-31-1

3-nitro-o-cresol

1-((2-methoxyethoxy)methoxy)-2-methyl-3-nitrobenzene
1628177-43-4

1-((2-methoxyethoxy)methoxy)-2-methyl-3-nitrobenzene

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 20℃; Inert atmosphere;82%
3-nitro-o-cresol
5460-31-1

3-nitro-o-cresol

Ethyl 2-bromopropionate
535-11-5, 41978-69-2

Ethyl 2-bromopropionate

ethyl 2-(2-methyl-3-nitrophenoxy)propanoate
97817-77-1

ethyl 2-(2-methyl-3-nitrophenoxy)propanoate

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide for 18h;80%
tert-Butyl 2,2,2-trichloroacetimidate
98946-18-0

tert-Butyl 2,2,2-trichloroacetimidate

3-nitro-o-cresol
5460-31-1

3-nitro-o-cresol

2-methyl-3-tert-butoxynitrobenzene
801282-13-3

2-methyl-3-tert-butoxynitrobenzene

Conditions
ConditionsYield
With boron trifluoride diethyl etherate In tetrahydrofuran; cyclohexane at 18 - 22℃; for 20h;78%
3-nitro-o-cresol
5460-31-1

3-nitro-o-cresol

2-propynyl chloride
624-65-7

2-propynyl chloride

2-Methyl-1-nitro-3-prop-2-ynyloxy-benzene
187267-84-1

2-Methyl-1-nitro-3-prop-2-ynyloxy-benzene

Conditions
ConditionsYield
With potassium carbonate In acetone for 12h; Heating;77%
3-nitro-o-cresol
5460-31-1

3-nitro-o-cresol

diphenyliodonium chloride
1483-72-3

diphenyliodonium chloride

2-methyl-1-nitro-3-phenoxybenzene
930790-12-8

2-methyl-1-nitro-3-phenoxybenzene

Conditions
ConditionsYield
Stage #1: 3-nitro-o-cresol With potassium tert-butylate In tetrahydrofuran at 0℃; for 0.25h;
Stage #2: diphenyliodonium chloride In tetrahydrofuran at 0 - 20℃;
77%
2-Iodobenzoic acid
88-67-5

2-Iodobenzoic acid

3-nitro-o-cresol
5460-31-1

3-nitro-o-cresol

2-(2-methyl-3-nitrophenoxy)benzoic acid
43160-01-6

2-(2-methyl-3-nitrophenoxy)benzoic acid

Conditions
ConditionsYield
With copper(l) iodide; copper; potassium carbonate In pentan-1-ol at 180℃; for 3h;76%
2-bromo-2-methylpropionic acid methyl ester
23426-63-3

2-bromo-2-methylpropionic acid methyl ester

3-nitro-o-cresol
5460-31-1

3-nitro-o-cresol

methyl 2-methyl-2-(2-methyl-3-nitrophenoxy)propanoate
748154-53-2

methyl 2-methyl-2-(2-methyl-3-nitrophenoxy)propanoate

Conditions
ConditionsYield
With potassium carbonate In DMF (N,N-dimethyl-formamide) at 95℃; for 72h;75%
With caesium carbonate In N,N-dimethyl-formamide at 100℃; for 96h;39%
3-nitro-o-cresol
5460-31-1

3-nitro-o-cresol

acetyl chloride
75-36-5

acetyl chloride

1-(2-hydroxy-3-methyl-4-nitrophenyl)ethanone
190730-40-6

1-(2-hydroxy-3-methyl-4-nitrophenyl)ethanone

Conditions
ConditionsYield
With aluminium trichloride In nitrobenzene 1.) 45 deg C, 1 h, 2.) 120 deg C, 16 h;72%
With aluminum (III) chloride In nitrobenzene at 120℃; for 12h;30.1%
With hydrogenchloride; sodium chloride; aluminium trichloride In dichloromethane; nitrobenzene
trans-6-benzyloxy-2-nitro-β-pyrrolindino -styrene

trans-6-benzyloxy-2-nitro-β-pyrrolindino -styrene

3-nitro-o-cresol
5460-31-1

3-nitro-o-cresol

acetic acid 1H-indol-4-yl ester
5585-96-6

acetic acid 1H-indol-4-yl ester

Conditions
ConditionsYield
With 2-(Dimethylamino)pyridine; acetic anhydride; triethylamine; palladium-carbon In ethyl acetate69%
3-nitro-o-cresol
5460-31-1

3-nitro-o-cresol

tert-butyldimethylsilyl chloride
18162-48-6

tert-butyldimethylsilyl chloride

(2-(bromomethyl)-3-nitrophenoxy)(tert-butyl)dimethylsilane
111742-62-2

(2-(bromomethyl)-3-nitrophenoxy)(tert-butyl)dimethylsilane

Conditions
ConditionsYield
Stage #1: 3-nitro-o-cresol; tert-butyldimethylsilyl chloride In tetrahydrofuran at 20℃;
Stage #2: With N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile) In tetrachloromethane for 3h; Irradiation using a sun lamp;
66%
Stage #1: 3-nitro-o-cresol; tert-butyldimethylsilyl chloride With 1H-imidazole In tetrahydrofuran at 20℃; for 12h;
Stage #2: With N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile) In tetrachloromethane for 3h; UV-irradiation;
66%

5460-31-1Relevant articles and documents

Synthetic method of 4-hydroxyindole

-

Paragraph 0039; 0051-0058, (2021/03/30)

The invention belongs to the technical field of organic synthesis, and particularly relates to a synthetic method of 4-hydroxyindole. Aiming at the problems existing in industrial production of 4-hydroxyindole in the prior art, the technical scheme of the invention is as follows: the method comprises the following steps: (1) protecting hydroxyl in a compound 3 by using a protective group to obtaina compound 4; (2) reacting the compound 4 with N, N-dimethylformamide dimethyl acetal to obtain a compound 5; (3) mixing the compound 5 with NH2NH2.H2O and MeOH, and carrying out a reaction to obtaina compound 6; and (4) removing the protective group of the compound 6 to obtain 4-hydroxyindole. According to the method for synthesizing 4-hydroxyindole, the cost of starting materials is low, the reaction conditions in the synthesis process are mild, operation is convenient, aftertreatment is simple, and the yield is high.

Catalytic asymmetric intramolecular hydroarylations of ω-aryloxy- and arylamino-tethered α,β-unsaturated aldehydes

Lu, Hai-Hua,Liu, Hui,Wu, Wei,Wang, Xu-Fan,Lu, Liang-Qiu,Xiao, Wen-Jing

supporting information; scheme or table, p. 2742 - 2746 (2009/12/03)

The first enantioselective organocatalytic intramolecular hydroarylations of phenol and aniline-derived enals were investigated. The proposed method provided an atom economic and straightforward approach to optically active chromans and tetrahydroquinolines in high enantioselectivities and in good yields. The study demonstrated the efficiency of organocatalysis to achieve the first asymmetric intramolecular arylation of ω aryloxy- arylamino-tethered α, and β-unsaturated aldehydes using a chiral secondary amine catalyst. Proposed transformation method resulted in the production of functionalized chromans and tetrahydroquinoline in high enantiopurity. The study also examined the scope of substrates in this organocatalytic reaction using a catalyst 4/p-TsOH.H2O in diethyl ether. The catalyst screening observed a higher yield up to 83% and comparable enantiometric excess up to 88% that can be obtained in a chiral secondary amine employed as the reaction catalyst.

Reaction of cerium(IV) ammonium nitrate with simple phenols in a silica gel matrix

Chakrabarty, K,Chawla, H M,Suresh, V V

, p. 464 - 466 (2007/10/02)

The oxophilicity of cerium(IV) ammonium nitrate is moderated by the addition of hydrogen peroxide.The reaction with simple phenols becomes regioselective when carried out in a silica gel matrix.The methodology has been employed for the synthesis of new functionalized terphenyls and biphenyls.

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