54646-54-7Relevant academic research and scientific papers
"Syn-Effect" in the Conversion of (E)-Vinylic Sulfones to the Corresponding Allylic Sulfones
Hirata, Takaki,Sasada, Yoshihiro,Ohtani, Takashi,Asada, Takahiro,Kinoshita, Hideki,et al.
, p. 75 - 96 (2007/10/02)
It was found that (E)-vinylic sulfones preferentially afford (Z)-allylic sulfones as kinetically-controlled products by treatment with a base under mild conditions, while (Z)-vinylic sulfones give (E)-allylic sulfones.Such stereochemical relationship was
A SIMPLE METHOD FOR THE SYNTHESIS OF γ-FUNCTIONALIZED VINYL AND ALLYL SULFONES
Najera, Carmen,Perez-Pinar, Alfonso,Sansano, Jose M.
, p. 6337 - 6352 (2007/10/02)
The synthesis of γ-functionalized vinyl sulfones 3 have been carried out directly starting from dibromides 2 derived from allyl sulfones 1 by reaction with different nucleophiles.The process is stereoselective affording compounds 3 with E configuration ex
