54718-72-8Relevant articles and documents
The Anomalous Reactions of Some Fluoronitrobenzenes with Some N,N-Dialkylamines
Gale, Douglas J.,Rosevear, Judi,Wilshire, John F. K.
, p. 997 - 1008 (1995)
The reactions of 1-fluoro-2,4,- and -2,6-dinitrobenzene with certain N,N-dilkylamines in dimethyl sulfoxide solution in the presence of potassium carbonate give the corresponding dinitrophenyl N,N-dialkylcarbamates as well as corresponding N,N-dialkyldinitroanilines.The extent of carbamate formation is governed by steric factors.The corresponding reactions of 1-fluoro-4-nitrobenzene with diisopropylamine and di-s-butylamine give poor yields of the corresponding 4-nitrophenyl N,N-dialkylcarbamates but none of the corresponding N,N-dialkyl-4-nitroanilines; in these reactions, the major product is 4,4'-dinitrodiphenyl ether.The 1H and 13C n.m.r. spectra of the 2,4- and 2,6-dinitrophenyl N,N-dialkylcarbamates reveal that their aliphatic protons and carbon atoms are magnetically non-equivalent.
