54722-14-4Relevant academic research and scientific papers
Ni-Catalyzed Asymmetric Hydrophosphination of Unactivated Alkynes
Gao, Li,Han, Xue-Yu,Huang, Zhuo,Liu, Xu-Teng,Sun, Ying-Ying,Wu, Yue,Zhang, Qing-Wei
supporting information, p. 11309 - 11316 (2021/08/03)
The practical synthesis of P-stereogenic tertiary phosphines, which have wide applications in asymmetric catalysis, materials, and pharmaceutical chemistry, represents a significant challenge. A regio- and enantioselective hydrophosphination using cheap a
Reduction of phosphinites, phosphinates, and related species with DIBAL-H
Busacca, Carl A.,Bartholomeyzik, Teresa,Cheekoori, Sreedhar,Raju, Ravinder,Eriksson, Magnus,Kapadia, Suresh,Saha, Anjan,Zeng, Xingzhong,Senanayake, Chris H.
body text, p. 287 - 291 (2009/07/01)
Diisobutylaluminium hydride has been found to be an excellent reducing agent for phosphinites, phosphinates, and chlorophosphines. By performing reductions in situ, direct synthesis of secondary phosphine boranes from Grignard reagents has been achieved without isolation or purification of any intermediates. Georg Thieme Verlag Stuttgart.
