54731-72-5Relevant articles and documents
SYNTHESIS AND PHARMACOLOGICAL ACTIVITY OF ALKYLPHOSPHONIC AND OXY DERIVATIVES
Tyurenkov, I. N.,Brel', A. K.,Strel'tsova, G. V.,Skladonovskaya, N. N.,Nazarenko, V. N.
, p. 120 - 123 (1988)
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Boutevin,Hervaud,Jeanmaire,Boulahna,Elasri
, p. 1 - 14 (2007/10/03)
This paper describes the synthesis and the characterization by 1H and 31P NMR of several monosalts and monoacids issued from phosphonates bearing alkyl groups (C1 to C18) or alkylene groups (allyl or vinyl). Functional compounds (alcohol or acetate) were also used and the results demonstrate the reaction selectivity. The method involves sodium iodide in ketones (acetone or 2-butanone) under reflux. It is very selective for monosalts, but only methyl phosphonates are very reactive. The corresponding acids were then obtained in quantitative yields with a cation exchange resin (sulfate acid).
Note on the Synthesis of β-Hydroxyethanephosphonic Acid
Gloede, J.,Weigt, E.,Gross, H.
, p. 327 - 328 (2007/10/02)
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