54743-54-3Relevant academic research and scientific papers
CATALYTIC PHOSPHORYLATION OF POLYFLUOROALKANOLS. 15. CATALYTIC PHOSPHORYLATION OF α-POLYFLUOROALKYLBENZYL ALCOHOLS BY BIS(POLYFLUOROALKYL) CHLOROPHOSPHATES
Goryunov, E. I.,Petrovskii, P. V.,Shcherbina, T. M.,Laretina, A. P.,Zakharov, L. S.,Kabachnik, M. I.
, p. 787 - 794 (2007/10/02)
The catalytic phosphorylation of α-polyfluoroalkylbenzyl alcohols by bis(polyfluoroalkyl) chlorophosphates is a convenient method for the synthesis of various bis(polyfluoroalkyl)(α-polyfluoroalkylbenzyl) phosphates, including those having donor substituents in the benzene ring.It was shown that in the series of p-methyl-α-trifluoromethylbenzyl phosphates p-CH3C6H4CH(CF3)OP(O)XY (where X, Y = Cl, CF3CH2O), the ability to act as O-alkylating agents with respect to polyfluorinated alcohols is a common characteristic, and the alkylating ability increases symbatically with increase in the overall electron-acceptor strength of the X and Y substituents at the phosphorus atom.
CATALYTIC PHOSPHORYLATION OF POLYFLUOROALKANOLS. 12. SYNTHESIS AND STEREOCHEMISTRY OF (1,1-DIHYDROPOLYFLUOROALKYL)(α-POLYFLUOROALKYLBENZYL) CHLOROPHOSPHATES
Goryunov, E. I.,Petrovskii, P. V.,Shcherbina, T. M.,Zakharov, L. S.,Kabachnik, M. I.
, p. 1700 - 1707 (2007/10/02)
Catalytic phosphorylation of α-polyfluoroalkylbenzyl alcohols with excess 1,1-dihydropolyfluoroalkyl dichlorophosphates afforded (1,1-dihydropolyfluoroalkyl)(α-polyfluoroalkylbenzyl) chlorophosphates in a high yield.According to NMR (1H, 19F, 31P) spectal
