54767-15-6Relevant academic research and scientific papers
Molecular structure of perfluoroadamantane from gas-phase electron diffraction
Hargittai, Istvan,Brunvoll, Jon,Sonoda, Takaaki,Takashi, Abe,Baba, Hajime
, p. 55 - 58 (1998)
The following bond lengths (r(g)) and bond angles have been determined for perfluomadamantane from gas-phase electron diffraction: C-C 1.560 ± 0.003, C(F2)-F 1.340 ± 0.005, C(F)-F 1.363 ± 0.010 A, CC(F2)C 107.7 ± 0.9, CC(F)C 110.3 ± 0.4, FC(F2)F 106.9 ± 0.4, C(F2)CF 108.6 ± 0.4 and C(F)CF 110.5 ± 0.2°. Perfluorination is found to expand the adamantane cage, characterized by a 0.02 A lengthening of the C-C bonds.
Functional group transformation of perfluoroadamantane derivatives
Murata, Koichi,Wang, Shu-Zhong,Morizawa, Yoshitomi,Oharu, Kazuya
, p. 1125 - 1129 (2008/09/16)
An adamantane skeleton, having rigid structure, has been used for a thermally stable and/or anti-etching material. It is expected to be a material having good optical properties, if fluorine atoms are introduced into the skeleton. Thus, the investigation concerning the functional group transformation of perfluoroadamantanecarboxylic acid derivatives was performed to develop the methods for introduction of perfluoroadamantyl group into molecules. Their unique reactivities are also discussed.
