54774-45-7Relevant academic research and scientific papers
Assignment of absolute configurations of permethrin and its synthon 3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylic acid by electronic circular dichroism, optical rotation, and X-ray crystallography
Bicker, Wolfgang,Kacprzak, Karol,Kwit, Marcin,Laemmerhofer, Michael,Gawronski, Jacek,Lindner, Wolfgang
experimental part, p. 1027 - 1035 (2009/10/10)
The availability of single stereoisomers of biologically/toxicologically relevant chiral compounds such as the pyrethroid-type insecticide permethrin (PM) and the reliable determination of their absolute configurations are of central importance for the de
Search for Routes of Synthesis of Permethrin and Chloropermethrin Starting from Halogen-containing Alkenoic Acids
Badanyan,Stepanyan,Mikaelyan,Ovivyan,Panosyan
, p. 34 - 41 (2007/10/03)
Promising procedures were developed for the synthesis of permethrin and I-chloropermethrin starting from acid chloride, nitrile, and esters of 3,3-dimethyl-2,2,4,6,6-pentachloro-5-alkenoic acid and 3,3-dimethyl-2,2,6,6-tetrachloro-5-alken-4-olide, which were prepared by adding derivatives of trichloroacetic acid to 1,1-dichloro-4-methyl-1,3-pentadiene in the presence of catalytic amounts of monovalent copper ions and amine.
New Chiral Agents for Resolution of Racemic cis-Permethric and cis-Z-cyhalothric Acids
Popov, Sergey A.,Tkachev, Alexey V.
, p. 1013 - 1018 (2007/10/03)
Resolution of racemic pyrethroid acids (cis-permethric and cis-Z-cyhalothric) using stable optically active amines derived from natural monoterpene (+)-3-carene and preparation of optically active esters of the pyrethroid acids are described.
