54774-47-9

Upstream product

• 76984-70-8 C₈H₉Cl₃O 
• 13826-35-2 3-Phenoxybenzyl alcohol 
• 51632-16-7 3-phenoxybenzyl bromide 
• 59042-49-8 cis-permethrinic acid 
• 55667-43-1 1,1-dichloro-4-methyl-penta-1,3-diene 
• 61976-30-5 methyl 2,2-dimethyl-3-(2,2-dichloroethenyl)cyclopropane-1-carboxylate 
• 61820-11-9 (+/-)-cis-2,2-dimethyl-3-(2',2'-dichlorovinyl)cyclopropanecarbonitrile 
• 202519-12-8 3,3-Dichloro-5-(2,2-dichloro-vinyl)-4,4-dimethyl-dihydro-furan-2-one 
• 202519-14-0 2,2,4,6,6-pentachloro-3,3-dimethylhex-5-enoic acid nitrile 
• 63406-23-5 methyl 4,6,6-trichloro-3,3-dimethyl-5-hexenoate 
• 61820-12-0 5-(2,2-dichlorovinyl)-4,4-dimethyl-2-oxotetrahydrofuran 

Downstream Products

• 59042-49-8 cis-permethrinic acid 
• 13826-35-2 3-Phenoxybenzyl alcohol 
• 64964-54-1 (1R,3S)-3-Chloroethynyl-2,2-dimethyl-cyclopropanecarboxylic acid 3-phenoxy-benzyl ester 

Relevant academic research and scientific papers

Assignment of absolute configurations of permethrin and its synthon 3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylic acid by electronic circular dichroism, optical rotation, and X-ray crystallography

The availability of single stereoisomers of biologically/toxicologically relevant chiral compounds such as the pyrethroid-type insecticide permethrin (PM) and the reliable determination of their absolute configurations are of central importance for the de

Search for Routes of Synthesis of Permethrin and Chloropermethrin Starting from Halogen-containing Alkenoic Acids

Promising procedures were developed for the synthesis of permethrin and I-chloropermethrin starting from acid chloride, nitrile, and esters of 3,3-dimethyl-2,2,4,6,6-pentachloro-5-alkenoic acid and 3,3-dimethyl-2,2,6,6-tetrachloro-5-alken-4-olide, which were prepared by adding derivatives of trichloroacetic acid to 1,1-dichloro-4-methyl-1,3-pentadiene in the presence of catalytic amounts of monovalent copper ions and amine.