547741-10-6Relevant academic research and scientific papers
Synthesis of 3-acyl-4-alkenylpyrrolidines by platinum-catalyzed hydrative cyclization of allenynes
Matsuda, Takanori,Kadowaki, Sho,Murakami, Masahiro
, p. 1672 - 1680 (2006)
A series of nitrogen-tethered allenynes ('5-aza-1,2-dien-7-ynes') 1 were transformed to the corresponding 3-acyl-4-alkenylpyrrolidines 3 when treated with a catalytic amount of PtCl2 in MeOH at 70°. Initial Pt-promoted cyclization forms a noncl
