547744-75-2

Upstream product

• 1119-51-3 bromopentene 
• 768-33-2 phenyldimethylsilyl chloride 
• 174710-92-0 [1,3]Dithian-2-yl-dimethyl-phenyl-silane 

Downstream Products

• 1141682-94-1 C₂₂H₃₄OSi 
• 1141682-82-7 (R)-3-(dimethyl(phenyl)silyl)-1-phenyl-oct-7-en-1-yn-3-ol 
• 1141682-92-9 rac-3-(dimethyl(phenyl)silyl)-1-phenyl-oct-7-en-1-yn-3-ol 
• 1141682-99-6 (R,R)-trans-2-methyl-1-(phenylethynyl)-cyclopentanol 
• 1141683-19-3 (S,S)-trans-2-methyl-1-(phenylethynyl)-cyclopentanol 
• 1237741-50-2 (1R,2R)-2-iodomethyl-1-(phenylethynyl)-cyclopentanol 

Relevant academic research and scientific papers

Ti(III)-Mediated Radical-Induced Approach to a Bicyclic δ-Lactone with a Bridgehead β-Hydroxy Group

Herein, we portray a synthetic route to a bicyclic lactone containing a bridgehead hydroxy group, a structure that is present in many natural products of biological and medicinal relevance. Ethyl (E)-3-(dimethylphenylsilyl)-7,8-epoxyoct-2-enoate underwent

Kinetic Resolution of Acylsilane Cyanohydrins via Organocatalytic Cycloetherification

An asymmetric cyanation of acylsilanes involving the in-situ formation of chiral acylsilane cyanohydrins followed by their kinetic resolution via organocatalytic cycloetherification is described. The highly enantio- and diastereoselective cycloetherificat