547765-34-4Relevant academic research and scientific papers
Bond energy M-C/H-C correlations: Dual theoretical and experimental approach to the sensitivity of M-C bond strength to substituents
Clot, Eric,Besora, Maria,Maseras, Feliu,Megret, Claire,Eisenstein, Odile,Oelckers, Beatriz,Perutz, Robin N.
, p. 490 - 491 (2003)
DFT methods are used to quantify the relationship between M-C and H-C bond energies; for MLn = Re(η5-C5H5)(CO)2H and fluorinated aryl ligands, theoretical and experimental investigations of ortho-fluorine substitution indicate a much larger increase in the M-C than in the H-C bond energy, so stabilising C-H activation products.
