54812-37-2

Basic information

• Product Name: Benzene, 2-iodo-1,3-dimethoxy-5-methyl-
• CAS NO: 54812-37-2
• Molecular Formula: C9H11IO2
• Molecular Weight: 278.09
• Mol File: 54812-37-2.mol

Chemical Properties

• CAS DataBase Reference: Benzene, 2-iodo-1,3-dimethoxy-5-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 2-iodo-1,3-dimethoxy-5-methyl-(54812-37-2)
• EPA Substance Registry System: Benzene, 2-iodo-1,3-dimethoxy-5-methyl-(54812-37-2)

Safety Data

• Hazardous Substances Data: 54812-37-2(Hazardous Substances Data)

Upstream product

• 16533-36-1 5-methyl-2-nitro-resorcinol 
• 112639-11-9 1,3-dihydroxy-2-iodo-5-methylbenzene 
• 74-88-4 methyl iodide 
• 54812-41-8 2,6-dimethoxy-4-methyl-aniline 
• 4179-19-5 1,3-dimethoxy-5-methylbenzene 
• 71867-46-4 3,5-dimethoxy-4-nitro-toluene 

Downstream Products

• 943911-90-8 C₂₁H₂₆O₄S 
• 26166-39-2 Ascochlorin 
• 943911-96-4 C₂₁H₂₅ClO₄S 
• 943911-93-1 C₃₁H₄₅ClO₈ 
• 943911-88-4 C₂₆H₃₃ClO₈S 
• 943911-92-0 C₂₄H₂₉ClO₇S 
• 943911-97-5 C₂₀H₂₁ClO₅S 
• 943911-91-9 C₂₂H₂₅ClO₅S 

Relevant articles and documents

Catalytic and chemoselective oxidation of activated alcohols and direct conversion of diols to lactones with in situ-generated bis-IBX catalyst

The twisted 3,3′-diiodo-2,2′,6,6′-tetramethoxybiphenyl-4, 4′-dicarboxylic acid (DIDA) was designed and synthesized for the in situ generation of Bis-IBX and catalytic oxidations. The seemingly better solubility of the in situ-generated Bis-IBX and the attenuated reactivity arising from its unique structural features and methoxy substituents allowed the catalytic oxidation of activated alcohols selectively using DIDA/oxone. Chemoselective oxidations were demonstrated for substrates containing two different hydroxy groups. Furthermore, the unique reactivity of DIDA was demonstrated for sequential oxidation reactions of 1,4- and 1,6-diols to give lactones catalytically in respectable yields.

Facile synthesis of (-)-ascochlorin using palladium-catalyzed three component coupling reaction

(-)-Ascochlorin was synthesized using palladium-catalyzed three component coupling reaction. Reaction of the aryl iodide 3, isoprene, and sodium p-toluenesulfinate in the presence of Pd2(dba)3CHCl 3 catalyst and NaHCO

Halogenation of Phenols and Phenyl Ethers with Potassium Halides in the Presence of 18-Crown-6 on Oxidation with m-Chloroperbenzoic Acid

Several types of phenyl ethers have been monobrominated in the ring in good yields with potassium bromide in the presence of 18-crown-6 on oxidation with m-chloroperbenzoic acid.Monoiodination takes place with both phenyl ethers and free phenols when potassium iodide is employed.