54813-80-8

Upstream product

• 100-44-7 benzyl chloride 
• 20414-58-8 methyl (E)-4-carbomethoxy-3-methoxy-2-butenoate 
• 1830-54-2 3-oxopentanedioic acid dimethyl ester 
• 640729-45-9 methyl (E)-4-carbomethoxy-4-benzyl-3-methoxy-2-butenoate 

Relevant academic research and scientific papers

Benzannulation of arynes with dimethylacetonedicarboxylates via an insertion-fragmentation-Dieckman-aromatization cascade: Expeditious entry to naphthoresorcinols and binaphthoresorcinols

Aryne insertions into 1,3,5-tricarbonyl bearing dimethylacetonedicarboxylate (DMAD) proceeds through a 4-step cascade process to eventuate in a versatile one pot synthesis of functionally embellished naphthoresorcinols. Functional group amplifications and

Alkylation of dimethyl 1,3-acetonedicarboxylate

A reliable, reproducible, general, and detailed procedure for the alkylation of dimethyl-1,3-acetonedicarboxylate are is described.