54815-45-1

Basic information

• Product Name: (ethoxysulfanyl)benzene
• CAS NO: 54815-45-1
• Molecular Formula: C₈H₁₀OS
• Molecular Weight: 154.2294
• Mol File: 54815-45-1.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 212.2°C at 760 mmHg
• Flash Point: 82.1°C
• Density: 1.07g/cm³
• Vapor Pressure: 0.255mmHg at 25°C
• Refractive Index: 1.551
• CAS DataBase Reference: (ethoxysulfanyl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: (ethoxysulfanyl)benzene(54815-45-1)
• EPA Substance Registry System: (ethoxysulfanyl)benzene(54815-45-1)

Safety Data

• Hazardous Substances Data: 54815-45-1(Hazardous Substances Data)

Usage

General Description

(Ethoxysulfanyl)benzene, also known as ethylthiophenol, is a chemical compound with the formula C8H10OS. It is a colorless to pale yellow liquid with a strong, unpleasant odor. (Ethoxysulfanyl)benzene is used as an intermediate in the synthesis of pharmaceuticals, fragrances, and other organic compounds. It is also used as a precursor for the production of rubber and as a solvent in the manufacture of dyes and chemicals. The compound is considered harmful if ingested, inhaled, or absorbed through the skin, and should be handled with care in industrial and laboratory settings.

Upstream product

• 64-17-5 ethanol 
• 100-68-5 methyl-phenyl-thioether 
• 882-33-7 diphenyldisulfane 
• 29959-86-2 1-(phenylsulphenyl)piperidylamide 
• 931-59-9 benzenesulfenyl chloride 

Downstream Products

• 882-33-7 diphenyldisulfane 
• 122602-92-0 (Z)-2-<(phenylthio)methylene>-3,3-dimethylbicyclo<2.2.1>heptane 
• 122602-93-1 (E)-2-<(phenylthio)methylene>-3,3-dimethylbicyclo<2.2.1>heptane 
• 4409-79-4 S-phenyl benzenethiosulfinate 
• 14032-04-3 trans-2-phenylthiocyclohexanol 
• 14032-03-2 1-chloro-2-phenylsulfanylcyclohexane 
• 100388-22-5 1-bromo-2-phenylsulfanylcyclohexane 
• 14032-03-2 ((1R,2R)-2-chlorocyclohexyl)(phenyl)sulfane 
• 54784-92-8 bromide of trans-2-phenylthiocyclohexane 
• 101384-19-4 2-Chloro-2,3-dimethyl-1-phenylthiobut-3-ene 
• 16728-17-9 3-Chlor-3-methyl-4-phenylmercapto-buten-⁽¹⁾ 
• 16728-18-0 2-Methyl-3-chlor-4-phenylmercapto-buten-⁽¹⁾ 
• 139259-62-4 ((E)-4-Chloro-2-methyl-but-2-enylsulfanyl)-benzene 

Relevant articles and documents

Synthesis of Sulfinamidines and Sulfinimidate Esters by Transfer of Nitrogen to Sulfenamides

In this work we report a new synthetic tactic for the straightforward preparation of hardly accessible sulfinamidines and sulfinamide esters, by using a simple metal-free protocol. The process is robust and uses readily available sulfenamides as the S-don

Experimental Tests of the Stereoelectronic Effect at Phosphorus: Nucleophilic Reactivity of Phosphite Esters

Triethyl phosphite rapidly reacts with ethyl benzenesulfenate or diethyl peroxide to yield pentaethoxyphosphorane.In contrast, 1-methyl-4-phospha-3,5,8-trioxabicyclooctane (1) fails to react with either electrophile to yield the expected bicyclic phosphorane 5.The poor reactivity of the bicyclic phosphite 1 is due to a kinetic rather than a thermodynamic barrier because 5 is formed smoothly from an equimolar mixture of P(OEt)5 and the triol 1,1,1-tris(hydroxymethyl)ethane.This result is interpreted in terms of the stereoelectronic effect.The order of nucleophilic reactivity of trialkyl phosphites with 3-benzylidene-2,4-pentanedione is also shown to be consistent with the stereoelectronic effect.The bicyclic phosphite 1 reacted 750 times slower than the pseudoequatorial 2-methoxy ester of hexahydrobenzo-1,3,2-dioxaphosphorinane in a Michael addition reaction with 3-benzylidene-2,4-pentanedione.