5482-06-4Relevant academic research and scientific papers
Buttressing Salicylaldehydes: A Multipurpose Directing Group for C(sp3)?H Bond Activation
Yada, Akira,Liao, Wenqing,Sato, Yuta,Murakami, Masahiro
supporting information, p. 1073 - 1076 (2017/01/18)
A palladium-catalyzed reaction of primary amines with iodoarenes produces γ-arylated primary amines. A bulky salicylaldehyde, which is marked as easily available, installable, removable, and recoverable, plays a key role in directing palladium to site-selectively activate the C?H bond located γ to the amino group.
The Electrochemical Synthesis of Neutral Zinc(II) Complexes of Schiff Base Ligands: The Crystal Structure of Biszinc(II)
Sogo, T.,Romero, J.,Sousa, A.,Blas, A. de,Duran, M. L.,Castellano, E. E.
, p. 611 - 615 (2007/10/02)
The electrochemical synthesis and physico-chemical properties of neutral zinc(II) complexes of bidentate Schiff bases derived from salicylaldehydes are presented together with the X-ray structure of biszinc(II).The crystal is monoclinic, a = 21.877(3), b = 8.801(2), c = 12.027(5) Angstroem, β = 96.55(3) deg, space group C2/c.The complex is a monomer, and the zinc atom is tetrahedrally coordinated. - Keywords: X-Ray, Zinc, Schiff Bases, Electrochemical Synthesis
Synthesis and Reactions of Phenolic Alkylbenzylnitrosamines
Bowman, Peter J.,Brown, Ben R.,Chapman, M. Andrew,Doyle, Paul M.
, p. 701 - 770 (2007/10/02)
N-Alkyl-p-hydroxybenzylnitrosamines have been synthesised from p-benzoyloxybenzaldehydes via imines and amines which were nitrosated before removal of the protecting group with n-propylamine.N-Alkyl-o-hydroxybenzylnitrosamines were similarly obtained from o-methoxymethoxybenzaldehydes, the final deprotection being achieved with dilute acid.The nitrosamines decompose in hot aqueous alkali by two mechanisms, one through a quinone methide to yield a benzyl alcohol and the other by an elimination eventually yielding a benzaldehyde.The decomposition of the nitrosamines in the presence of 2-naphthol in alkaline solution results in alkylation of the naphthol and production of compounds from the reaction of 2-naphthol with the intermediate quinone methides.The N-sec-butylnitrosamines alkylate 2-naphthol on carbon but the N-methylnitrosamines alkylate on oxygen and during the methylation 94percent of deuterium exchange with methyl hydrogen occurs in deuterium oxide and there is 6percent intact transfer of the methyl group from the N-methylnitrosamine to the 2-naphthol.
N-Substituted Salicylaldimines Derivatives of Germanium(IV)
Singh, R. V.,Tandon, J. P.
, p. 1391 - 1398 (2007/10/02)
Hexa-coordinated Schiff base complexes of germanium of the general type Ge(OC2H5)2(SB)2 (SB(-) is the anion of the monofunctional bidentate Schiff base, SBH) have been synthesized by the reaction between ethyl-orthogermanate and the Schiff base in benzene
