54841-08-6Relevant academic research and scientific papers
Bridged carbocyclic compounds and methods of making and using same
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Page/Page column 27, (2010/02/10)
Disclosed herein is a fluorinated bridged carbocyclic compound that can be polymerized by itself or with at least one other ethylenically unsaturated monomer to provide a polymer. The polymer may be used, for example, within a sub-300 nm photoresist compo
Facile preparation and synthetic applications of LiCH2C(CF3)2Oli
Grushin, Vladimir V.,Marshall, William J.,Halliday, Gary A.,Davidson, Fredric,Petrov, Viacheslav A.
, p. 121 - 129 (2007/10/03)
Bromohydrin BrCH2C(CF3)2OH readily reacts with two equivalents of n-BuLi at - 78 °C to produce the corresponding dilithium derivative LiCH2C(CF3)2OLi in high yield. This dilithiated derivative reacts selectively, acting as a C-nucleophile, with a variety of electrophiles such as R2PCl, carbonyl compounds, and epoxides, to give electron-deficient phosphines R2PCH2C(CF3)2OH, 1,3- and 1,4-diols, correspondingly.
Fluorinated compounds
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, (2008/06/13)
1,1,4,4-Tetrakis(trifluoromethyl)butan-1,4-diol and 1,1-bis (trifluoromethyl)propanol-1 are prepared by reacting gaseous hexafluoroacetone and ethane in a transparent container in the presence of sunlight. The diol is a crystalline solid and the propanol-1 is a liquid. The diol is useful as a monomer in the field of polymer chemistry. That is, polymers such as polyurethans and polyesters which find many applications in the chemical industry can be made by reacting the proper material with the diol of this invention. The propanol-1 is useful as a plasticizer for polyurethans and other plastics.
