548477-36-7

Upstream product

• 221015-48-1 (1R,5R,7S)-7-(tert-Butyl-dimethyl-silanyloxymethyl)-6,8-dioxa-bicyclo[3.2.1]oct-3-en-2-one 
• 243987-99-7 (1S,2R,5R,7S)-7-(tert-Butyl-dimethyl-silanyloxymethyl)-6,8-dioxa-bicyclo[3.2.1]oct-3-en-2-ol 
• 548477-30-1 (1S,2S,5R,7S)-7-(tert-Butyl-dimethyl-silanyloxymethyl)-6,8-dioxa-bicyclo[3.2.1]oct-3-en-2-ol 
• 548477-34-5 (5S,6R)-5-Allyloxy-6-vinyl-tetrahydro-pyran-2-ol 
• 548477-35-6 (4R,5R)-4-Allyloxy-hept-6-ene-1,5-diol 
• 548477-32-3 ((1S,2S,5R,7S)-2-Allyloxy-6,8-dioxa-bicyclo[3.2.1]oct-7-yl)-methanol 
• 548477-33-4 (1S,2S,5S,7R)-2-Allyloxy-7-iodomethyl-6,8-dioxa-bicyclo[3.2.1]octane 
• 548477-31-2 (1S,2S,5R,7S)-7-(tert-Butyl-dimethyl-silanyloxymethyl)-6,8-dioxa-bicyclo[3.2.1]octan-2-ol 

Downstream Products

• 548477-38-9 2-{6-[3-(tert-butyl-diphenyl-silanyloxy)-propyl]-3,6-dihydro-2H-pyran-3-yl}-N,N-dimethyl-acetamide 
• 548477-39-0 2-{6-[3-(tert-butyl-diphenyl-silanyloxy)-propyl]-tetrahydro-pyran-3-yl}-N,N-dimethyl-acetamide 

Relevant academic research and scientific papers

A stereocontrolled synthesis of (+)-rhopaloic acid a using a dioxabicyclo[3.2.1]octane chiral building block

Utilizing a chiral building block having a dioxabicyclo[3.2.1]octane framework, (+)-rhopaloic acid A, a potent cytotoxic norsesterterpene isolated from the marine sponge Rhopaloeides sp., has been synthesized in a stereocontrolled manner.