54881-57-1Relevant articles and documents
Viriot-Villaume et al.
, p. 3301 (1974)
Tandem decarboxylative allylation and fragmentation of allyl benzocyclobutenyl carbonates: Access to ortho-functionalized aryls from aryl bromides
Rosa, David,Chtchemelinine, Andrei,Orellana, Arturo
, p. 1885 - 1891 (2012/08/14)
Allyl benzocyclobutyl carbonates yield ortho-allyl α-aryl ketones through a palladium-catalyzed decarboxylative allylation, fragmentation, and cross-coupling process. Georg Thieme Verlag Stuttgart · New York.
DECOMPOSITION ACIDO-CATALYSEE D'AZIDES TERTIAIRES BENZOCYCLOBUTENIQUES. NOUVELLE METHODE DE SYNTHESE DU NOYAU INDOLIQUE PAR EXTENSION DU CYCLE
Adam, G.,Andrieux, J.,Plat, M
, p. 399 - 408 (2007/10/02)
Treatment of benzocyclobutenols substituted on the functional carbon by the HN3/BF3-Et2O reagent allows the synthesis to the corresponding tertiary azides.The latter by acid-catalysed breakdown, lead to 2-substituted indoles.A similar result is obtained by treating directly the alcohols with hydrazoic acid and concentrated sulfuric acid.This new route to indole nucleus is also extended to the synthesis of policyclic indoles.