54884-49-0Relevant academic research and scientific papers
6,6-Dicyanopentafulvenes: Electronic structure and regioselectivity in [2 + 2] cycloaddition-retroelectrocyclization reactions
Finke, Aaron D.,Dumele, Oliver,Zalibera, Michal,Confortin, Daria,Cias, Pawel,Jayamurugan, Govindasamy,Gisselbrecht, Jean-Paul,Boudon, Corinne,Schweizer, W. Bernd,Gescheidt, Georg,Diederich, Francois
, p. 18139 - 18146 (2013/01/15)
We present an investigation of the electronic properties and reactivity behavior of electron-accepting 6,6-dicyanopentafulvenes (DCFs). The electron paramagnetic resonance (EPR) spectra of the radical anion of a tetrakis(silylalkynyl) DCF, generated by Na
Synthesis, reactivity, and electronic properties of 6,6-dicyanofulvenes
Andrew, Trisha L.,Cox, Jason R.,Swager, Timothy M.
supporting information; experimental part, p. 5302 - 5305 (2011/02/21)
A series of 6,6-dicyanofulvene derivatives are synthesized starting from masked, dimeric, or monomeric cyclopentadienones. The reactivities of 6,6-dicyanofulvenes relative to their parent cyclopentadienones are discussed. 6,6-Dicyanofulvenes are capable o
