54888-46-9Relevant academic research and scientific papers
FLUORINATION OF POLYFLUOROAROMATIC COMPOUNDS WITH VANADIUM PENTAFLUORIDE
Bardin, V. V.,Avramenko, A. A.,Furin, G. G.,Yakobson, G. G.,Krasilnikov, V. A.,et al.
, p. 37 - 46 (1985)
Fluorination of polyfluoro-derivatives of benzene and diphenyl with vanadium pentafluoride at -25 to -10 deg C afforded fluorinated cyclohexadienes and cyclohexenes.Octafluoronaphthalene was converted under these conditions to perfluoro-1,4-dihydronaphthalene, perfluorotetralin, perfluoro-1,4,5,8-tetrahydronaphthalene and perfluoro-1,2,3,4,5,8-hexahydronaphthalene.
AROMATIC FLUORINE DERIVATIVES. XCVII. OXIDATIVE FLUORINATION OF PERFLUORINATED AROMATIC COMPOUNDS WITH VANADIUM PENTAFLUORIDE
Bardin, V. V.,Furin, G. G.,Avramenko, A. A.,Krasil'nikov, V. A.,Tushin, P. P.,et all
, p. 307 - 311 (2007/10/02)
Perfluorinated aromatic compounds are converted by the action of vanadium pentafluoride at -25 to -15 deg C into perfluorinated derivatives of cyclohexadiene and cyclohexene.The rate of addition of the two fluorine atoms to the perfluorinated derivatives of 1,3- and 1,4-cyclohexadiene under conditions of competing fluorination depends on the nature of the substituent at the carbon-carbon double bond.
