54905-16-7

Upstream product

• 3561-67-9 bis(phenylthio)methane 
• 106-95-6 allyl bromide 
• 4832-52-4 tris(phenylthio)methane 
• 762-72-1 allyl-trimethyl-silane 

Downstream Products

• 53097-28-2 (E/Z)-1-(phenylthio)buta-1,3-diene 
• 98793-19-2 5-hydroxy-4,4-bisphenylthiohept-1-ene 
• 1256169-05-7 1-(2-hydroxyphenyl)-2-methyl-4,4-bis(phenylthio)butan-1-one 
• 128099-28-5 C₂₇H₂₈S₃ 
• 128099-28-5 C₂₇H₂₈S₃ 
• 128099-19-4 4-Methyl-3,5,5-tris-phenylsulfanyl-oct-7-en-2-ol 
• 128099-04-7 (2R,3R)-3-Methyl-2,4,4-tris-phenylsulfanyl-hept-6-en-1-ol 
• 128099-09-2 3-Methyl-2,4,4-tris-phenylsulfanyl-hept-6-enal 
• 98793-34-1 4,5-bisphenylthiohepta-1,3-diene 
• 98793-50-1 3,4-bisphenylthiohepta-2,4-diene 
• 128098-71-5 methyl (2RS,3RS)-3-methyl-2,4,4-tris(phenylthio)hept-6-enoate 
• 128098-71-5 (2S,3R)-3-Methyl-2,4,4-tris-phenylsulfanyl-hept-6-enoic acid methyl ester 
• 128098-83-9 (3RS,4RS)-2,4-dimethyl-3,5,5-tris(phenylthio)oct-7-en-2-ol 
• 128098-95-3 5,7-dimethyl-4,4-bisphenylthioocta-1,6-diene 

Relevant academic research and scientific papers

Regio- and enantioselective intermolecular hydroacylation: Substrate-directed addition of salicylaldehydes to homoallylic sulfides

We report a Rh-catalyzed, regio- and enantioselective intermolecular olefin hydroacylation under mild conditions. Hydroacylations between homoallylic sulfides, containing a substrate-bound directing group, and salicylaldehyde derivatives occur in the presence of a spiro-phosphoramidite ligand, (R)-SIPHOS-PE, to give α-branched ketones in >20:1 selectivity and up to 97% ee. Our conditions are also applicable to the asymmetric intermolecular hydroacylation of 1,2-disubstituted olefins.

Lewis acid-catalyzed coupling reactions of allylsilanes with tris(phenylchalcogeno)methane. Synthesis of homoallylchalcogenoacetals

Reaction of allylsilanes with tris(phenylseleno)methane or tris(phenylthio)methane in the presence of a Lewis acid furnishes the corresponding homoallylchalcogenoacetals in moderate to good yields.

Generation, Some Synthetic Uses, and 1,2-Vinyl Rearrangements of Secondary and Tertiary Homoallyllithiums, Including Ring Contractions and A Ring Expansion. Remarkable Acceleration of the Rearrangement by an Oxyanionic Group

A very general preparative method for homoallyllithiums consists of reductive lithiation of homoallylithiums consists of reductive lithiation of homoallyl phenyl sulfides by lithium 4,4'-di-tert-butylbiphenylide.The sulfides can be prepared by a variety o

Phenylthio Migrations in Rearrangements of 2,2-Bisphenylthioethanols

Thionyl chloride causes rearrangement of the title compounds to give 2,3-bisphenylthiopropenes (12) by a phenylthio shift.The products undergo phenylthio shifts on exposure to light.Some applications to synthesis are described.