54931-72-5Relevant academic research and scientific papers
An organocatalyst bound α-aminoalkyl radical intermediate for controlled aerobic oxidation of iminium ions
Motaleb, Abdul,Bera, Asish,Maity, Pradip
supporting information, p. 5081 - 5085 (2018/07/29)
A catalyst bound α-aminoalkyl radical intermediate from iminium is developed to control its formation and reactivity with aerobic oxygen. The influence of the catalyst was demonstrated via the ease of radical intermediate formation and its subsequent reactivity, including the first catalyst-controlled enantioselective aerobic oxidation with a chiral phosphite catalyst.
Iridium(III)-Catalyzed Regiocontrolled Direct Amidation of Isoquinolones and Pyridones
Das, Debapratim,Samanta, Rajarshi
, p. 379 - 384 (2017/12/26)
Iridium(III)-catalyzed highly regiocontrolled C3/C8 amidation of isoquinolones and C6 amidation of 2-pyridones has been successfully accomplished with various azides. The optimized method is operationally simple with a broad substrate scope. The protocol has been found to be scalable. (Figure presented.).
Gold vs Rhodium Catalysis: Tuning Reactivity through Catalyst Control in the C-H Alkynylation of Isoquinolones
Shaikh, Aslam C.,Shinde, Dinesh R.,Patil, Nitin T.
, p. 1056 - 1059 (2016/03/15)
A site-selective C-4/C-8 alkynylation of isoquinolones catalyzed by gold and rhodium complexes is reported. A broad range of synthetically useful functional groups (-F, -Cl, -Br, -CF3, -OMe, alkyl, etc.) were tolerated, providing an efficient a
