54932-87-5Relevant academic research and scientific papers
Contra-Thermodynamic Positional Isomerization of Olefins
Zhao, Kuo,Knowles, Robert R.
supporting information, p. 137 - 144 (2022/01/19)
A light-driven method for the contra-thermodynamic positional isomerization of olefins is described. In this work, stepwise PCET activation of a more substituted and more thermodynamically stable olefin substrate is mediated by an excited-state oxidant an
Nickel-catalyzed deallylation of aryl allyl ethers with hydrosilanes
Wang, Jingyang,Wang, Yu,Ding, Guangni,Wu, Xiaoyu,Yang, Liqun,Fan, Sijie,Zhang, Zhaoguo,Xie, Xiaomin
, (2021/09/28)
An efficient and mild catalytic deallylation method of aryl allyl ethers is developed, with commercially available Ni(COD)2 as catalyst precursor, simple substituted bipyridine as ligand and air-stable hydrosilanes. The process is compatible with a variety of functional groups and the desired phenol products can be obtained with excellent yields and selectivity. Besides, by detection or isolation of key intermediates, mechanism studies confirm that the deallylation undergoes η3-allylnickel intermediate pathway.
Pd-Catalyzed regioselective hydroesterification of 2-allylphenols to seven-membered lactones without external CO gas
Chang, Wenju,Li, Jingfu,Ren, Wenlong,Shi, Yian
supporting information, p. 3047 - 3052 (2016/03/19)
Effective Pd-catalyzed regioselective hydroesterification of 2-allylphenols with phenyl formate is described. A variety of seven-membered lactones can be obtained in good yields under mild conditions without the use of toxic CO gas.
Synthesis and structure of [Ru(PPh3)2(bipy)(MeCN)Cl][BPh4] and it's catalytic property towards regioselective and stereoselective allylation of phenols
Sinha, Abhilasha,Khatua, Snehadrinarayan,Bhattacharjee, Manish
supporting information, p. 116 - 120 (2015/02/19)
The compound, [Ru(PPh3)2(bipy)(MeCN)Cl][BPh4] (1) has been synthesized from the precursor complex, [Ru(bipy)(PPh3)2Cl2]. The complex has been structurally characterized. This complex has been found to be an efficient catalyst for the regioselective allylation of phenols.
OXAZOLOBENZIMIDAZOLE DERIVATIVES
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Page/Page column 12, (2011/04/18)
The present invention is directed to oxazolobenzimidazole derivatives which are potentiators of metabotropic glutamate receptors, particularly the mGluR2 receptor, and which are useful in the treatment or prevention of neurological and psychiatric disorde
Mo(CO)6 catalyzed one-pot conversion of allyl aryl ethers to dihydrobenzofurans
Bernard, Angela M.,Cocco, Maria T.,Onnis, Valentina,Piras, Pier P.
, p. 41 - 43 (2007/10/03)
Molybdenum hexacarbonyl effectively catalyses a tandem Claisen rearrangement-cyclization reaction of allyl aryl ethers to give good yields of dihydrobenzofurans.
