549514-48-9Relevant academic research and scientific papers
Gold(I) Phosphido Complexes: Synthesis, Structure, and Reactivity
Stefanescu, Diana M.,Yuen, Holming F.,Glueck, David S.,Golen, James A.,Zakharov, Lev N.,Incarvito, Christopher D.,Rheingold, Arnold L.
, p. 8891 - 8901 (2008/10/09)
Deprotonation of the phosphine complexes Au(PHR2)Cl with aqueous ammonia gave the gold(I) phosphido complexes [Au(PR2)] n (PR2 = PMes2 (1), PCy2 (2), P(t-Bu)2 (3), PIs2/sub
Synthesis and structure of cyclic gold(I) phosphanyl complexes [{Au(PR2)}n]
Stefanescu, Diana M.,Yuen, Holming F.,Glueck, David S.,Golen, James A.,Rheingold, Arnold L.
, p. 1046 - 1048 (2007/10/03)
Gold(I) Phosphanyl Complexes, such as [Au(PR2)]n, have been known for more than 25 years. However, the solid-state structure of such complexes, as well as their nature in solution, has remained somewhat of a mystery. The figure displays the cyclic and polymeric forms that are possible (L = endgroup). The structures of the complexes, and the occurrence of Au...Au interactions are discussed.
