54953-03-6

Usage

Uses

Used in Pharmaceutical Industry:
[1-(4-methoxyphenyl)-2,2-dimethylpropylidene]hydrazine is used as a building block for the synthesis of other organic compounds, particularly in the pharmaceutical industry. Its unique molecular structure may offer novel properties and functionalities that can be exploited in the development of new drugs.
Used in Agrochemical Industry:
In the agrochemical industry, [1-(4-methoxyphenyl)-2,2-dimethylpropylidene]hydrazine may be utilized as an intermediate in the production of various agrochemicals, such as pesticides or herbicides, due to its reactive functional groups and potential for further chemical modification.
Used in Materials Science:
[1-(4-methoxyphenyl)-2,2-dimethylpropylidene]hydrazine's molecular structure also suggests potential applications in materials science. It could be used as a component in the development of new materials with specific properties, such as improved stability, reactivity, or other desirable characteristics.

Upstream product

• 2040-26-8 1-(4-methoxyphenyl)-2,2-dimethyl-1-propanone 

Downstream Products

• 2040-26-8 1-(4-methoxyphenyl)-2,2-dimethyl-1-propanone 
• 133861-36-6 (p-Methoxyphenyl)tert-butyldiazomethane 
• 54953-04-7 2,5-di-tert-butyl-2,5-bis-(4-methoxy-phenyl)-2,5-dihydro-[1,3,4]thiadiazole 1,1-dioxide 
• 79289-18-2 4-anisyl tert-butyl ketone α-chloroacetylhydrazone 

Relevant academic research and scientific papers

Formation and Reactivity of ?-Radical Cation Intermediates in the C-C Coupling Reaction of Phenyldiazomethanes by One-Electron Oxidation

One-electron oxidation of phenyldiazomethanes afforded cis-stilbene predominantly.The reaction was independent of the oxidation methods, e.g., electrolysis, copper(II), triarylaminium salts, or photosensitized one-electron oxidtions.The C-C coupling reaction was retarded by introducing α-substituents on phenyldiazomethanes.The ESR spectra of diazoalkane radical cations could be obtained during the electrolysis at low temperature and the resulting spectra revealed their unique electronic structure as ?-radicals for most cases.When a bulky tert-butyl group was substituted, the corresponding ?-radical cation was observed, but the C-C coupling reaction did not occur.The novel HOMO-LUMO switching by one-electron removal from the HOMO ?-orbital of diazomethane is explained by the interaction of phenyl group with the C-N-N ?-radical moiety.The C-C coupling reaction proceeds via facile cycloaddition between the diazomethane and ?-radical cation, and the preferential formation of cis-olefins is based on the secondary orbital interaction between the two phenyl groups.The structure and the stability of radical cation intermediates are rationalized on the basis of ab initio calculations.