55007-44-8Relevant academic research and scientific papers
Aminyl Radical Generation via Tandem Norrish Type i Photocleavage, β-Fragmentation: Independent Generation and Reactivity of the 2′-Deoxyadenosin- N6-yl Radical
Zheng, Liwei,Griesser, Markus,Pratt, Derek A.,Greenberg, Marc M.
, p. 3571 - 3580 (2017)
Formal hydrogen atom abstraction from the nitrogen-hydrogen bonds in purine nucleosides produces reactive intermediates that are important in nucleic acid oxidation. Herein we describe an approach for the independent generation of the purine radical resul
NOUVELLES METHODES DE DESHALOGENATION ET DE FORMATION D'ETHERS D'ENOL TRIMETHYLSILYLIQUES PAR ACTION DE iPr2NLi SUR QUELQUES α-MONOBROMO- ET α,α'-DIBROMOCETONES
Lion, Claude,Dubois, Jacques-Emile,Lebbar, Khadija
, p. 119 - 126 (2007/10/02)
Attempts to prepare 2-bromo-2,4-dimethyl,3-trimethylsiloxy 3-pentene reacting lithium diisopropylamide (LDA) with 2-bromo-2,4-dimethyl-3 pentanone have revealed two new reactions.After a few minutes quantitative yields are obtained of either the dehalogenated ketone (after hydrolysis) or the trimethylsilyl enol ether (after addition of trimethylsilyl chloride).These reactions are general and have been extended to other α-monobromoketones and α,α'-dibromoketones.In the latter case, the reaction is more complex and leads generally to dehalogenation or reduction products.
