550364-48-2Relevant academic research and scientific papers
Trienylboronic acid, a versatile coupling tool for retinoid synthesis; Stereospecific synthesis of 13-aryl substituted (11Z)-retinal
Uenishi, Jun'ichi,Matsui, Katsuaki,Wada, Akimori
, p. 3093 - 3096 (2007/10/03)
Trienylboronic acid 1a was prepared from iodotriene 3, which was coupled with (2Z,4Z)-3-aryl-5-iodo-2,4-pentadienol 9 by Suzuki coupling reaction to give geometrically pure 13-aryl substituted (11Z)-retinol 10. Oxidation of 10 gave 13-aryl substituted (11Z)-retinal 11.
