55065-37-7Relevant academic research and scientific papers
3-Chloro-propenyl esters in organic synthesis: A new chromium-catalysed homoaldol reaction
Lombardo, Marco,Morganti, Stefano,Licciulli, Sebastiano,Trombini, Claudio
, p. 43 - 46 (2007/10/03)
Chromium(II) oxidatively adds to 3-halo-propenyl esters affording heterosubstituted allylchromium(III) reagents exploitable in the Nozaki-Hiyama-Kishi reaction. A catalytic cycle based on the Cr(III)-Mn(0) redox couple was applied, affording protected homoaldols as the major products, at 65 °C in acetonitrile as solvent.
