55111-01-8Relevant academic research and scientific papers
ORGANIC SYNTHESIS WITH REAGENTS DERIVED FROM 3R3SiMgMe AND MnCl2
Fugami, Keigo,Hibino, Jun-ichi,Nakatsukasa, Shigeki,Matsubara, Seijiro,Oshima, Koichiro,et al.
, p. 4277 - 4292 (2007/10/02)
Synthetically useful reactions mediated by reagents derived from 3 equiv. of R3SiMgMe and MnCl2 are disclosed. (1) The manganese species reacted with terminal acetylenes to give 1,2-disilylated 1-alkenes.Mono- and bis(trimethylsilyl)acetylenes gave tri- a
NEW SYNTHESES OF VINYLSILANES AND ALLYLSILANES BY CROSS-COUPLING OF (R3Si)3MnMgMe WITH ALKENYL AND ALLYLIC COMPOUNDS
Fugami, Keigo,Oshima, Koichiro,Utimoto, Kiitiro,Nozaki, Hitosi
, p. 2161 - 2164 (2007/10/02)
The reaction of alkenyl halides, alkenyl sulfides, and enol phosphates with (R3Si)3MnMgMe provides vinylsilanes in good yields.The method is also applicable to the allylsilane synthesis from allylic sulfides and ethers.
